Highly Performance Core-Shell TiO(2)(B)/anatase Homojunction Nanobelts with Active Cobalt phosphide Cocatalyst for Hydrogen Production

In this paper, a highly efficient core-shell structure of TiO(2)(B)/anatase photocatalyst with CoP cocatalyst has been synthesized via hydrothermal processes and a mechanical milling method. The designed core-shell TiO(2)(B)/anatase photocatalysts exhibit excellent performance by compared with pure TiO(2)(B) and anatase phase. With the participation of CoP particles, there is drastically enhanced photocatalytic activity of TiO(2)(B)/anatase, and the H(2)-production rate can be up to 7400 μmol·g(−1), which is about 3.2 times higher than TiO(2)(B)/anatase photocatalyst. The improved activity is attributed to the contribution of the well-matched core-shell structure and cooperative effect of CoP cocatalyst. The photogenerated holes of anatase can migrate more promptly to the adjacent TiO(2)(B) core than the photogenerated electrons, which result in an accumulation of electrons in the anatase, and CoP nanoparticles can contribute significantly to transferring electrons from the surface of TiO(2)(A). It was found that the efficient separation of electron-hole pairs greatly improved the photocatalytic hydrogen evolution in water under UV light irradiation.