Crystalline boron-linked tetraaminoethylene radical cations

Single-electron oxidation of neutral boryl-linked tetraaminoethylene derivatives 4 led to the formation of radical cations 4˙(+) , which have been isolated and fully characterized. X-ray diffraction analysis, EPR spectroscopy, and computational studies revealed that the unpaired electron is delocali...

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Autores principales: Su, Yuanting, Li, Yongxin, Ganguly, Rakesh, Kinjo, Rei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5674142/
https://www.ncbi.nlm.nih.gov/pubmed/29163893
http://dx.doi.org/10.1039/c7sc03528d
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author Su, Yuanting
Li, Yongxin
Ganguly, Rakesh
Kinjo, Rei
author_facet Su, Yuanting
Li, Yongxin
Ganguly, Rakesh
Kinjo, Rei
author_sort Su, Yuanting
collection PubMed
description Single-electron oxidation of neutral boryl-linked tetraaminoethylene derivatives 4 led to the formation of radical cations 4˙(+) , which have been isolated and fully characterized. X-ray diffraction analysis, EPR spectroscopy, and computational studies revealed that the unpaired electron is delocalized over the B(2)N(4)C(2) skeleton and the spin density mainly resides on the carbon and boron atoms.
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spelling pubmed-56741422017-11-21 Crystalline boron-linked tetraaminoethylene radical cations Su, Yuanting Li, Yongxin Ganguly, Rakesh Kinjo, Rei Chem Sci Chemistry Single-electron oxidation of neutral boryl-linked tetraaminoethylene derivatives 4 led to the formation of radical cations 4˙(+) , which have been isolated and fully characterized. X-ray diffraction analysis, EPR spectroscopy, and computational studies revealed that the unpaired electron is delocalized over the B(2)N(4)C(2) skeleton and the spin density mainly resides on the carbon and boron atoms. Royal Society of Chemistry 2017-11-01 2017-09-12 /pmc/articles/PMC5674142/ /pubmed/29163893 http://dx.doi.org/10.1039/c7sc03528d Text en This journal is © The Royal Society of Chemistry 2017 https://creativecommons.org/licenses/by/3.0/This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/ (https://creativecommons.org/licenses/by/3.0/) ) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Su, Yuanting
Li, Yongxin
Ganguly, Rakesh
Kinjo, Rei
Crystalline boron-linked tetraaminoethylene radical cations
title Crystalline boron-linked tetraaminoethylene radical cations
title_full Crystalline boron-linked tetraaminoethylene radical cations
title_fullStr Crystalline boron-linked tetraaminoethylene radical cations
title_full_unstemmed Crystalline boron-linked tetraaminoethylene radical cations
title_short Crystalline boron-linked tetraaminoethylene radical cations
title_sort crystalline boron-linked tetraaminoethylene radical cations
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5674142/
https://www.ncbi.nlm.nih.gov/pubmed/29163893
http://dx.doi.org/10.1039/c7sc03528d
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AT liyongxin crystallineboronlinkedtetraaminoethyleneradicalcations
AT gangulyrakesh crystallineboronlinkedtetraaminoethyleneradicalcations
AT kinjorei crystallineboronlinkedtetraaminoethyleneradicalcations

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