Cargando…

Crystalline boron-linked tetraaminoethylene radical cations

Single-electron oxidation of neutral boryl-linked tetraaminoethylene derivatives 4 led to the formation of radical cations 4˙(+) , which have been isolated and fully characterized. X-ray diffraction analysis, EPR spectroscopy, and computational studies revealed that the unpaired electron is delocali...

Descripción completa

Detalles Bibliográficos
Autores principales:	Su, Yuanting, Li, Yongxin, Ganguly, Rakesh, Kinjo, Rei
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5674142/ https://www.ncbi.nlm.nih.gov/pubmed/29163893 http://dx.doi.org/10.1039/c7sc03528d

Ejemplares similares

Ambiphilic boron in 1,4,2,5-diazadiborinine
por: Wang, Baolin, et al.
Publicado: (2016)

1,3,2,5-Diazadiborinine featuring nucleophilic and electrophilic boron centres
por: Wu, Di, et al.
Publicado: (2015)

Diverse reactivity of a tricoordinate organoboron L(2)PhB: (L = oxazol-2-ylidene) towards alkali metal, group 9 metal, and coinage metal precursors
por: Kong, Lingbing, et al.
Publicado: (2015)

Reversible [4 + 2] cycloaddition reaction of 1,3,2,5-diazadiborinine with ethylene
por: Wu, Di, et al.
Publicado: (2015)

Boron-based stepwise dioxygen activation with 1,4,2,5-diazadiborinine
por: Wang, Baolin, et al.
Publicado: (2018)

Unraveling the reactivity of a cationic iminoborane: avenues to unusual boron cations
por: Guo, Rui, et al.
Publicado: (2022)

Crystalline Divinyldiarsene Radical Cations and Dications
por: Sharma, Mahendra K., et al.
Publicado: (2019)

A linear Di-coordinate boron radical cation
por: Lin, Yu-Jiang, et al.
Publicado: (2022)

Diaryldichalcogenide radical cations
por: Mallow, Ole, et al.
Publicado: (2015)

Radical boron migration of allylboronic esters
por: Tao, Xiangzhang, et al.
Publicado: (2022)

Electronic and valleytronic properties of crystalline boron-arsenide tuned by strain and disorder
por: Craco, L., et al.
Publicado: (2023)

A crystalline T-shaped planar group 14 anion
por: Liu, Xiaona, et al.
Publicado: (2023)

Boron Nitride Nanotube Addition Enhances the Crystallinity and Cytocompatibility of PVDF-TrFE
por: Poudel, Anup, et al.
Publicado: (2019)

Boron-containing delocalised lipophilic cations for the selective targeting of cancer cells
por: Gianpiero, Calabrese, et al.
Publicado: (2016)

Isolation of a Cyclic (Alkyl)(amino)germylene
por: Wang, Liliang, et al.
Publicado: (2016)

Correction: Boron-containing delocalised lipophilic cations for the selective targeting of cancer cells
por: Calabrese, Gianpiero, et al.
Publicado: (2017)

Mechanisms of IR amplification in radical cation polarons
por: Kendrick, William J., et al.
Publicado: (2020)

Laser vibrational excitation of radicals to prevent crystallinity degradation caused by boron doping in diamond
por: Fan, L., et al.
Publicado: (2021)

A supramolecular radical cation: folding-enhanced electrostatic effect for promoting radical-mediated oxidation
por: Tang, Bohan, et al.
Publicado: (2018)

Open questions in boron species with globally 4n π systems
por: Ota, Kei, et al.
Publicado: (2021)

Arenium cation or radical cation? An insight into the cyclodehydrogenation reaction of 2-substituted binaphthyls mediated by Lewis acids
por: Camargo Solórzano, Patricia, et al.
Publicado: (2020)

Selective multifunctionalization of N-heterocyclic carbene boranes via the intermediacy of boron-centered radicals
por: Li, Feng-Xing, et al.
Publicado: (2023)

Spontaneous Water Radical Cation Oxidation at Double Bonds in Microdroplets
por: Qiu, Lingqi, et al.
Publicado: (2022)

Superhard Boron-Rich Boron Carbide with Controlled Degree of Crystallinity
por: Chakrabarty, Kallol, et al.
Publicado: (2020)

Switching of the solid-state guest selectivity: solvent-dependent selective guest inclusion in a crystalline macrocyclic boronic ester
por: Ito, Suguru, et al.
Publicado: (2016)

Highly planar diarylamine-fused porphyrins and their remarkably stable radical cations
por: Fukui, Norihito, et al.
Publicado: (2017)

Aromaticity and sterics control whether a cationic olefin radical is resistant to disproportionation
por: Messelberger, Julian, et al.
Publicado: (2020)

Hydrophosphination of boron–boron multiple bonds
por: Stennett, Tom E., et al.
Publicado: (2019)

Aromatic nature of neutral and dianionic 1,4-diaza-2,3,5,6-tetraborinine derivatives
por: Ota, Kei, et al.
Publicado: (2021)

Correction: Aromaticity and sterics control whether a cationic olefin radical is resistant to disproportionation
por: Messelberger, Julian, et al.
Publicado: (2021)

Variations in Crystalline Structures and Electrical Properties of Single Crystalline Boron Nitride Nanosheets
por: Aldalbahi, Ali, et al.
Publicado: (2015)

Unstrained C–C bond activation and directed fluorination through photocatalytically-generated radical cations
por: Pitts, Cody Ross, et al.
Publicado: (2015)

A crystalline radical cation derived from Thiele’s hydrocarbon with redox range beyond 1 V
por: Loh, Ying Kai, et al.
Publicado: (2021)

Core functionalization of semi-crystalline polymeric cylindrical nanoparticles using photo-initiated thiol–ene radical reactions
por: Sun, Liang, et al.
Publicado: (2016)

Three-component 1,2-carboamination of vinyl boronic esters via amidyl radical induced 1,2-migration
por: You, Cai, et al.
Publicado: (2021)

Synthesis of Highly Crystalline Multilayered Boron Niride Microflakes
por: Ahmad, Pervaiz, et al.
Publicado: (2016)

Using Ylide Functionalization to Stabilize Boron Cations
por: Scherpf, Thorsten, et al.
Publicado: (2017)

Chemically Cross-Linked Cellulose Nanocrystal Aerogels for Effective Removal of Cation Dye
por: Liang, Luna, et al.
Publicado: (2020)

Linking metal–organic cages pairwise as a design approach for assembling multivariate crystalline materials
por: Markwell-Heys, Adrian W., et al.
Publicado: (2021)

Boron-containing capsaicinoids
por: Melanson, Jennifer A., et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_0d5o8blrb8ikebukieaf79ot0n