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Comparisons of lanthanide/actinide +2 ions in a tris(aryloxide)arene coordination environment
A new series of Ln(3+) and Ln(2+) complexes has been synthesized using the tris(aryloxide)arene ligand system, (((Ad,Me)ArO)(3)mes)(3–), recently used to isolate a complex of U(2+). The triphenol precursor, ((Ad,Me)ArOH)(3)mes, reacts with the Ln(3+) amides, Ln(NR(2))(3) (R = SiMe(3)), to form a ser...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5674182/ https://www.ncbi.nlm.nih.gov/pubmed/29163894 http://dx.doi.org/10.1039/c7sc02337e |