Mechanistic investigation of the formation of H(2) from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase

We report the mechanistic investigation of catalytic H(2) evolution from formic acid in water using a formate-bridged dinuclear Ru complex as a formate hydrogen lyase model. The mechanistic study is based on isotope-labeling experiments involving hydrogen isotope exchange reaction.

Detalles Bibliográficos
Autores principales: Tokunaga, Taisuke, Yatabe, Takeshi, Matsumoto, Takahiro, Ando, Tatsuya, Yoon, Ki-Seok, Ogo, Seiji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Taylor & Francis 2017
Materias:
Focus on Carbon-neutral Energy Science and Technology
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5678451/
https://www.ncbi.nlm.nih.gov/pubmed/29152019
http://dx.doi.org/10.1080/14686996.2017.1379857
Descripción
Sumario:We report the mechanistic investigation of catalytic H(2) evolution from formic acid in water using a formate-bridged dinuclear Ru complex as a formate hydrogen lyase model. The mechanistic study is based on isotope-labeling experiments involving hydrogen isotope exchange reaction.

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