Mechanistic investigation of the formation of H(2) from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase

We report the mechanistic investigation of catalytic H(2) evolution from formic acid in water using a formate-bridged dinuclear Ru complex as a formate hydrogen lyase model. The mechanistic study is based on isotope-labeling experiments involving hydrogen isotope exchange reaction.

Detalles Bibliográficos
Autores principales: Tokunaga, Taisuke, Yatabe, Takeshi, Matsumoto, Takahiro, Ando, Tatsuya, Yoon, Ki-Seok, Ogo, Seiji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Taylor & Francis 2017
Materias:
Focus on Carbon-neutral Energy Science and Technology
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5678451/
https://www.ncbi.nlm.nih.gov/pubmed/29152019
http://dx.doi.org/10.1080/14686996.2017.1379857
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author Tokunaga, Taisuke
Yatabe, Takeshi
Matsumoto, Takahiro
Ando, Tatsuya
Yoon, Ki-Seok
Ogo, Seiji
author_facet Tokunaga, Taisuke
Yatabe, Takeshi
Matsumoto, Takahiro
Ando, Tatsuya
Yoon, Ki-Seok
Ogo, Seiji
author_sort Tokunaga, Taisuke
collection PubMed
description We report the mechanistic investigation of catalytic H(2) evolution from formic acid in water using a formate-bridged dinuclear Ru complex as a formate hydrogen lyase model. The mechanistic study is based on isotope-labeling experiments involving hydrogen isotope exchange reaction.
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spelling pubmed-56784512017-11-17 Mechanistic investigation of the formation of H(2) from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase Tokunaga, Taisuke Yatabe, Takeshi Matsumoto, Takahiro Ando, Tatsuya Yoon, Ki-Seok Ogo, Seiji Sci Technol Adv Mater Focus on Carbon-neutral Energy Science and Technology We report the mechanistic investigation of catalytic H(2) evolution from formic acid in water using a formate-bridged dinuclear Ru complex as a formate hydrogen lyase model. The mechanistic study is based on isotope-labeling experiments involving hydrogen isotope exchange reaction. Taylor & Francis 2017-11-01 /pmc/articles/PMC5678451/ /pubmed/29152019 http://dx.doi.org/10.1080/14686996.2017.1379857 Text en © 2017 The Author(s). Published by National Institute for Materials Science in partnership with Taylor & Francis http://creativecommons.org/licenses/by/4.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Focus on Carbon-neutral Energy Science and Technology
Tokunaga, Taisuke
Yatabe, Takeshi
Matsumoto, Takahiro
Ando, Tatsuya
Yoon, Ki-Seok
Ogo, Seiji
Mechanistic investigation of the formation of H(2) from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase
title Mechanistic investigation of the formation of H(2) from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase
title_full Mechanistic investigation of the formation of H(2) from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase
title_fullStr Mechanistic investigation of the formation of H(2) from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase
title_full_unstemmed Mechanistic investigation of the formation of H(2) from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase
title_short Mechanistic investigation of the formation of H(2) from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase
title_sort mechanistic investigation of the formation of h(2) from hcooh with a dinuclear ru model complex for formate hydrogen lyase
topic Focus on Carbon-neutral Energy Science and Technology
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5678451/
https://www.ncbi.nlm.nih.gov/pubmed/29152019
http://dx.doi.org/10.1080/14686996.2017.1379857
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AT yatabetakeshi mechanisticinvestigationoftheformationofh2fromhcoohwithadinuclearrumodelcomplexforformatehydrogenlyase
AT matsumototakahiro mechanisticinvestigationoftheformationofh2fromhcoohwithadinuclearrumodelcomplexforformatehydrogenlyase
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