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Mechanistic investigation of the formation of H(2) from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase
We report the mechanistic investigation of catalytic H(2) evolution from formic acid in water using a formate-bridged dinuclear Ru complex as a formate hydrogen lyase model. The mechanistic study is based on isotope-labeling experiments involving hydrogen isotope exchange reaction.
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Taylor & Francis
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5678451/ https://www.ncbi.nlm.nih.gov/pubmed/29152019 http://dx.doi.org/10.1080/14686996.2017.1379857 |