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Self-organization of helium precipitates into elongated channels within metal nanolayers

Material degradation due to precipitation of implanted helium (He) is a key concern in nuclear energy. Decades of research have mapped out the fate of He precipitates in metals, from nucleation and growth of equiaxed bubbles and voids to formation and bursting of surface blisters. By contrast, we sh...

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Autores principales: Chen, Di, Li, Nan, Yuryev, Dina, Baldwin, J. Kevin, Wang, Yongqiang, Demkowicz, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5681214/
https://www.ncbi.nlm.nih.gov/pubmed/29152573
http://dx.doi.org/10.1126/sciadv.aao2710
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author Chen, Di
Li, Nan
Yuryev, Dina
Baldwin, J. Kevin
Wang, Yongqiang
Demkowicz, Michael J.
author_facet Chen, Di
Li, Nan
Yuryev, Dina
Baldwin, J. Kevin
Wang, Yongqiang
Demkowicz, Michael J.
author_sort Chen, Di
collection PubMed
description Material degradation due to precipitation of implanted helium (He) is a key concern in nuclear energy. Decades of research have mapped out the fate of He precipitates in metals, from nucleation and growth of equiaxed bubbles and voids to formation and bursting of surface blisters. By contrast, we show that He precipitates confined within nanoscale metal layers depart from their classical growth trajectories: They self-organize into elongated channels. These channels form via templated nucleation of He precipitates along layer surfaces followed by their growth and spontaneous coalescence into stable precipitate lines. The total line length and connectivity increases with the amount of implanted He, indicating that these channels ultimately interconnect into percolating “vascular” networks. Vascularized metal composites promise a transformative solution to He-induced damage by enabling in operando outgassing of He and other impurities while maintaining material integrity.
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spelling pubmed-56812142017-11-17 Self-organization of helium precipitates into elongated channels within metal nanolayers Chen, Di Li, Nan Yuryev, Dina Baldwin, J. Kevin Wang, Yongqiang Demkowicz, Michael J. Sci Adv Research Articles Material degradation due to precipitation of implanted helium (He) is a key concern in nuclear energy. Decades of research have mapped out the fate of He precipitates in metals, from nucleation and growth of equiaxed bubbles and voids to formation and bursting of surface blisters. By contrast, we show that He precipitates confined within nanoscale metal layers depart from their classical growth trajectories: They self-organize into elongated channels. These channels form via templated nucleation of He precipitates along layer surfaces followed by their growth and spontaneous coalescence into stable precipitate lines. The total line length and connectivity increases with the amount of implanted He, indicating that these channels ultimately interconnect into percolating “vascular” networks. Vascularized metal composites promise a transformative solution to He-induced damage by enabling in operando outgassing of He and other impurities while maintaining material integrity. American Association for the Advancement of Science 2017-11-10 /pmc/articles/PMC5681214/ /pubmed/29152573 http://dx.doi.org/10.1126/sciadv.aao2710 Text en Copyright © 2017 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC). http://creativecommons.org/licenses/by-nc/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution-NonCommercial license (http://creativecommons.org/licenses/by-nc/4.0/) , which permits use, distribution, and reproduction in any medium, so long as the resultant use is not for commercial advantage and provided the original work is properly cited.
spellingShingle Research Articles
Chen, Di
Li, Nan
Yuryev, Dina
Baldwin, J. Kevin
Wang, Yongqiang
Demkowicz, Michael J.
Self-organization of helium precipitates into elongated channels within metal nanolayers
title Self-organization of helium precipitates into elongated channels within metal nanolayers
title_full Self-organization of helium precipitates into elongated channels within metal nanolayers
title_fullStr Self-organization of helium precipitates into elongated channels within metal nanolayers
title_full_unstemmed Self-organization of helium precipitates into elongated channels within metal nanolayers
title_short Self-organization of helium precipitates into elongated channels within metal nanolayers
title_sort self-organization of helium precipitates into elongated channels within metal nanolayers
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5681214/
https://www.ncbi.nlm.nih.gov/pubmed/29152573
http://dx.doi.org/10.1126/sciadv.aao2710
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