Synthesis and crystal structure of [Pd{C(6)H(4)(CH(2)NHCH(2)Ph)-2-κ(2) C,N}(μ-I)](2)

The binuclear title complex, di-μ-iodido-bis(­{2-[(benzylamino-κN)meth­yl]phenyl-κC (1)}palladium(II)), [Pd(2)I(2)(C(14)H(14)N)(2)], was prepared by reaction of [Pd{C(6)H(4)(CH(2)NHCH(2)Ph)-2}(μ-OAc)](2) with NaI. It crystallizes with one discrete mol­ecule in the asymmetric unit. The mol­ecule pres...

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Detalles Bibliográficos
Autores principales: Bautista, Delia, Benitez-Benitez, Sergio J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683475/
https://www.ncbi.nlm.nih.gov/pubmed/29152335
http://dx.doi.org/10.1107/S2056989017014281
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author Bautista, Delia
Benitez-Benitez, Sergio J.
author_facet Bautista, Delia
Benitez-Benitez, Sergio J.
author_sort Bautista, Delia
collection PubMed
description The binuclear title complex, di-μ-iodido-bis(­{2-[(benzylamino-κN)meth­yl]phenyl-κC (1)}palladium(II)), [Pd(2)I(2)(C(14)H(14)N)(2)], was prepared by reaction of [Pd{C(6)H(4)(CH(2)NHCH(2)Ph)-2}(μ-OAc)](2) with NaI. It crystallizes with one discrete mol­ecule in the asymmetric unit. The mol­ecule presents an iodide-bridged dimeric structure with a cisoid arrangement with respect to the C,N-cyclo­palladated ligands. Both Pd(II) atoms have a slightly distorted square-planar coordination environment. Weak inter­molecular contacts of the type C—H⋯Pd seem to have a significant influence on the arrangement of the mol­ecules along the b axis in the crystal.
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spelling pubmed-56834752017-11-17 Synthesis and crystal structure of [Pd{C(6)H(4)(CH(2)NHCH(2)Ph)-2-κ(2) C,N}(μ-I)](2) Bautista, Delia Benitez-Benitez, Sergio J. Acta Crystallogr E Crystallogr Commun Research Communications The binuclear title complex, di-μ-iodido-bis(­{2-[(benzylamino-κN)meth­yl]phenyl-κC (1)}palladium(II)), [Pd(2)I(2)(C(14)H(14)N)(2)], was prepared by reaction of [Pd{C(6)H(4)(CH(2)NHCH(2)Ph)-2}(μ-OAc)](2) with NaI. It crystallizes with one discrete mol­ecule in the asymmetric unit. The mol­ecule presents an iodide-bridged dimeric structure with a cisoid arrangement with respect to the C,N-cyclo­palladated ligands. Both Pd(II) atoms have a slightly distorted square-planar coordination environment. Weak inter­molecular contacts of the type C—H⋯Pd seem to have a significant influence on the arrangement of the mol­ecules along the b axis in the crystal. International Union of Crystallography 2017-10-06 /pmc/articles/PMC5683475/ /pubmed/29152335 http://dx.doi.org/10.1107/S2056989017014281 Text en © Bautista and Benitez-Benitez 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Bautista, Delia
Benitez-Benitez, Sergio J.
Synthesis and crystal structure of [Pd{C(6)H(4)(CH(2)NHCH(2)Ph)-2-κ(2) C,N}(μ-I)](2)
title Synthesis and crystal structure of [Pd{C(6)H(4)(CH(2)NHCH(2)Ph)-2-κ(2) C,N}(μ-I)](2)
title_full Synthesis and crystal structure of [Pd{C(6)H(4)(CH(2)NHCH(2)Ph)-2-κ(2) C,N}(μ-I)](2)
title_fullStr Synthesis and crystal structure of [Pd{C(6)H(4)(CH(2)NHCH(2)Ph)-2-κ(2) C,N}(μ-I)](2)
title_full_unstemmed Synthesis and crystal structure of [Pd{C(6)H(4)(CH(2)NHCH(2)Ph)-2-κ(2) C,N}(μ-I)](2)
title_short Synthesis and crystal structure of [Pd{C(6)H(4)(CH(2)NHCH(2)Ph)-2-κ(2) C,N}(μ-I)](2)
title_sort synthesis and crystal structure of [pd{c(6)h(4)(ch(2)nhch(2)ph)-2-κ(2) c,n}(μ-i)](2)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683475/
https://www.ncbi.nlm.nih.gov/pubmed/29152335
http://dx.doi.org/10.1107/S2056989017014281
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