Green synthesis and crystal structure of 3-(benzo­thia­zol-2-yl)thio­phene

The title compound, C(11)H(7)NS(2), was prepared in high yield (87%) using a solvent-free microwave-assisted synthesis. The structure shows whole-mol­ecule disorder with occupancies for two orientations (A and B) of 0.4884 (10) and 0.5116 (10), respectively. The thio­phene and benzo­thia­zole rings...

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Detalles Bibliográficos
Autores principales: Nguyen Ngoc, Linh, Vu Quoc, Trung, Duong Quoc, Hoan, Vu Quoc, Manh, Truong Minh, Luong, Thang Pham, Chien, Van Meervelt, Luc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683482/
https://www.ncbi.nlm.nih.gov/pubmed/29152342
http://dx.doi.org/10.1107/S2056989017014530
Descripción
Sumario:The title compound, C(11)H(7)NS(2), was prepared in high yield (87%) using a solvent-free microwave-assisted synthesis. The structure shows whole-mol­ecule disorder with occupancies for two orientations (A and B) of 0.4884 (10) and 0.5116 (10), respectively. The thio­phene and benzo­thia­zole rings are almost planar and make dihedral angles of 10.02 (18) and 12.54 (19)° for orientations A and B, respectively. Slipped π–π stacking between the aromatic rings, together with C—H⋯π, C—H⋯S and C—H⋯N inter­actions, result in a herringbone motif in the crystal packing.

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