Cargando…
Hybrid organic–inorganic crystal structure of 4-(dimethylamino)pyridinium dimethylammonium tetrachloridolead(II)
The title compound, (C(2)H(8)N)(C(7)H(11)N(2))[PbCl(4)], is a hybrid organic–inorganic material. It crystallizes in the space group C2/c and contains one half of a molecule of lead chloride, 4-(dimethylamino)pyridinium, and dimethylammonium in the asymmetric unit. The crystal structure exhibit...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683487/ https://www.ncbi.nlm.nih.gov/pubmed/29152347 http://dx.doi.org/10.1107/S2056989017014062 |
Sumario: | The title compound, (C(2)H(8)N)(C(7)H(11)N(2))[PbCl(4)], is a hybrid organic–inorganic material. It crystallizes in the space group C2/c and contains one half of a molecule of lead chloride, 4-(dimethylamino)pyridinium, and dimethylammonium in the asymmetric unit. The crystal structure exhibits chains of lead chloride capped by 4-(dimethylamino)pyridinium and dimethylammoium by hydrogen bonding. This creates a one-dimensional zipper-like structure down the a axis. The crystal structure is examined and compared to a similar structure containing lead chloride and dimethylbenzene-1,4-diaminium. |
---|