Cargando…

Hybrid organic–inorganic crystal structure of 4-(di­methyl­amino)­pyridinium di­methyl­ammonium tetra­chlorido­lead(II)

The title compound, (C(2)H(8)N)(C(7)H(11)N(2))[PbCl(4)], is a hybrid organic–inorganic material. It crystallizes in the space group C2/c and contains one half of a mol­ecule of lead chloride, 4-(di­methyl­amino)­pyridinium, and di­methyl­ammonium in the asymmetric unit. The crystal structure exhibit...

Descripción completa

Detalles Bibliográficos
Autores principales: Benson, Cassidy A., Bateman, Gage, Cox, Jordan M., Benedict, Jason B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683487/
https://www.ncbi.nlm.nih.gov/pubmed/29152347
http://dx.doi.org/10.1107/S2056989017014062
Descripción
Sumario:The title compound, (C(2)H(8)N)(C(7)H(11)N(2))[PbCl(4)], is a hybrid organic–inorganic material. It crystallizes in the space group C2/c and contains one half of a mol­ecule of lead chloride, 4-(di­methyl­amino)­pyridinium, and di­methyl­ammonium in the asymmetric unit. The crystal structure exhibits chains of lead chloride capped by 4-(di­methyl­amino)­pyridinium and di­methyl­ammoium by hydrogen bonding. This creates a one-dimensional zipper-like structure down the a axis. The crystal structure is examined and compared to a similar structure containing lead chloride and di­methyl­benzene-1,4-diaminium.