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Hybrid organic–inorganic crystal structure of 4-(dimethylamino)pyridinium dimethylammonium tetrachloridolead(II)
The title compound, (C(2)H(8)N)(C(7)H(11)N(2))[PbCl(4)], is a hybrid organic–inorganic material. It crystallizes in the space group C2/c and contains one half of a molecule of lead chloride, 4-(dimethylamino)pyridinium, and dimethylammonium in the asymmetric unit. The crystal structure exhibit...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2017
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683487/ https://www.ncbi.nlm.nih.gov/pubmed/29152347 http://dx.doi.org/10.1107/S2056989017014062 |
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author | Benson, Cassidy A. Bateman, Gage Cox, Jordan M. Benedict, Jason B. |
author_facet | Benson, Cassidy A. Bateman, Gage Cox, Jordan M. Benedict, Jason B. |
author_sort | Benson, Cassidy A. |
collection | PubMed |
description | The title compound, (C(2)H(8)N)(C(7)H(11)N(2))[PbCl(4)], is a hybrid organic–inorganic material. It crystallizes in the space group C2/c and contains one half of a molecule of lead chloride, 4-(dimethylamino)pyridinium, and dimethylammonium in the asymmetric unit. The crystal structure exhibits chains of lead chloride capped by 4-(dimethylamino)pyridinium and dimethylammoium by hydrogen bonding. This creates a one-dimensional zipper-like structure down the a axis. The crystal structure is examined and compared to a similar structure containing lead chloride and dimethylbenzene-1,4-diaminium. |
format | Online Article Text |
id | pubmed-5683487 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-56834872017-11-17 Hybrid organic–inorganic crystal structure of 4-(dimethylamino)pyridinium dimethylammonium tetrachloridolead(II) Benson, Cassidy A. Bateman, Gage Cox, Jordan M. Benedict, Jason B. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, (C(2)H(8)N)(C(7)H(11)N(2))[PbCl(4)], is a hybrid organic–inorganic material. It crystallizes in the space group C2/c and contains one half of a molecule of lead chloride, 4-(dimethylamino)pyridinium, and dimethylammonium in the asymmetric unit. The crystal structure exhibits chains of lead chloride capped by 4-(dimethylamino)pyridinium and dimethylammoium by hydrogen bonding. This creates a one-dimensional zipper-like structure down the a axis. The crystal structure is examined and compared to a similar structure containing lead chloride and dimethylbenzene-1,4-diaminium. International Union of Crystallography 2017-10-20 /pmc/articles/PMC5683487/ /pubmed/29152347 http://dx.doi.org/10.1107/S2056989017014062 Text en © Benson et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Benson, Cassidy A. Bateman, Gage Cox, Jordan M. Benedict, Jason B. Hybrid organic–inorganic crystal structure of 4-(dimethylamino)pyridinium dimethylammonium tetrachloridolead(II) |
title | Hybrid organic–inorganic crystal structure of 4-(dimethylamino)pyridinium dimethylammonium tetrachloridolead(II) |
title_full | Hybrid organic–inorganic crystal structure of 4-(dimethylamino)pyridinium dimethylammonium tetrachloridolead(II) |
title_fullStr | Hybrid organic–inorganic crystal structure of 4-(dimethylamino)pyridinium dimethylammonium tetrachloridolead(II) |
title_full_unstemmed | Hybrid organic–inorganic crystal structure of 4-(dimethylamino)pyridinium dimethylammonium tetrachloridolead(II) |
title_short | Hybrid organic–inorganic crystal structure of 4-(dimethylamino)pyridinium dimethylammonium tetrachloridolead(II) |
title_sort | hybrid organic–inorganic crystal structure of 4-(dimethylamino)pyridinium dimethylammonium tetrachloridolead(ii) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683487/ https://www.ncbi.nlm.nih.gov/pubmed/29152347 http://dx.doi.org/10.1107/S2056989017014062 |
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