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Hybrid organic–inorganic crystal structure of 4-(di­methyl­amino)­pyridinium di­methyl­ammonium tetra­chlorido­lead(II)

The title compound, (C(2)H(8)N)(C(7)H(11)N(2))[PbCl(4)], is a hybrid organic–inorganic material. It crystallizes in the space group C2/c and contains one half of a mol­ecule of lead chloride, 4-(di­methyl­amino)­pyridinium, and di­methyl­ammonium in the asymmetric unit. The crystal structure exhibit...

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Detalles Bibliográficos
Autores principales: Benson, Cassidy A., Bateman, Gage, Cox, Jordan M., Benedict, Jason B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683487/
https://www.ncbi.nlm.nih.gov/pubmed/29152347
http://dx.doi.org/10.1107/S2056989017014062
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author Benson, Cassidy A.
Bateman, Gage
Cox, Jordan M.
Benedict, Jason B.
author_facet Benson, Cassidy A.
Bateman, Gage
Cox, Jordan M.
Benedict, Jason B.
author_sort Benson, Cassidy A.
collection PubMed
description The title compound, (C(2)H(8)N)(C(7)H(11)N(2))[PbCl(4)], is a hybrid organic–inorganic material. It crystallizes in the space group C2/c and contains one half of a mol­ecule of lead chloride, 4-(di­methyl­amino)­pyridinium, and di­methyl­ammonium in the asymmetric unit. The crystal structure exhibits chains of lead chloride capped by 4-(di­methyl­amino)­pyridinium and di­methyl­ammoium by hydrogen bonding. This creates a one-dimensional zipper-like structure down the a axis. The crystal structure is examined and compared to a similar structure containing lead chloride and di­methyl­benzene-1,4-diaminium.
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spelling pubmed-56834872017-11-17 Hybrid organic–inorganic crystal structure of 4-(di­methyl­amino)­pyridinium di­methyl­ammonium tetra­chlorido­lead(II) Benson, Cassidy A. Bateman, Gage Cox, Jordan M. Benedict, Jason B. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, (C(2)H(8)N)(C(7)H(11)N(2))[PbCl(4)], is a hybrid organic–inorganic material. It crystallizes in the space group C2/c and contains one half of a mol­ecule of lead chloride, 4-(di­methyl­amino)­pyridinium, and di­methyl­ammonium in the asymmetric unit. The crystal structure exhibits chains of lead chloride capped by 4-(di­methyl­amino)­pyridinium and di­methyl­ammoium by hydrogen bonding. This creates a one-dimensional zipper-like structure down the a axis. The crystal structure is examined and compared to a similar structure containing lead chloride and di­methyl­benzene-1,4-diaminium. International Union of Crystallography 2017-10-20 /pmc/articles/PMC5683487/ /pubmed/29152347 http://dx.doi.org/10.1107/S2056989017014062 Text en © Benson et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Benson, Cassidy A.
Bateman, Gage
Cox, Jordan M.
Benedict, Jason B.
Hybrid organic–inorganic crystal structure of 4-(di­methyl­amino)­pyridinium di­methyl­ammonium tetra­chlorido­lead(II)
title Hybrid organic–inorganic crystal structure of 4-(di­methyl­amino)­pyridinium di­methyl­ammonium tetra­chlorido­lead(II)
title_full Hybrid organic–inorganic crystal structure of 4-(di­methyl­amino)­pyridinium di­methyl­ammonium tetra­chlorido­lead(II)
title_fullStr Hybrid organic–inorganic crystal structure of 4-(di­methyl­amino)­pyridinium di­methyl­ammonium tetra­chlorido­lead(II)
title_full_unstemmed Hybrid organic–inorganic crystal structure of 4-(di­methyl­amino)­pyridinium di­methyl­ammonium tetra­chlorido­lead(II)
title_short Hybrid organic–inorganic crystal structure of 4-(di­methyl­amino)­pyridinium di­methyl­ammonium tetra­chlorido­lead(II)
title_sort hybrid organic–inorganic crystal structure of 4-(di­methyl­amino)­pyridinium di­methyl­ammonium tetra­chlorido­lead(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683487/
https://www.ncbi.nlm.nih.gov/pubmed/29152347
http://dx.doi.org/10.1107/S2056989017014062
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