Cargando…
Crystal structure of {2,6-bis[(dimethylamino)methyl]phenyl-κ(3) N,C (1),N′}(bromido/chlorido)mercury(II)
In the molecular structure of the title compound, {2,6-bis[(dimethylamino)methyl]phenyl-κ(3) N,C (1),N′}[bromido/chlorido(0.30/0.70)]mercury(II)–{2,6-bis[(dimethylamino)methyl]phenyl-κ(3) N,C (1),N′}[bromido/chlorido(0.24/0.76)]mercury(II) (1/1), [HgBr(0.30)Cl(0.70)(C(12)H(19)N(2))]·[H...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683489/ https://www.ncbi.nlm.nih.gov/pubmed/29152349 http://dx.doi.org/10.1107/S2056989017014682 |
Sumario: | In the molecular structure of the title compound, {2,6-bis[(dimethylamino)methyl]phenyl-κ(3) N,C (1),N′}[bromido/chlorido(0.30/0.70)]mercury(II)–{2,6-bis[(dimethylamino)methyl]phenyl-κ(3) N,C (1),N′}[bromido/chlorido(0.24/0.76)]mercury(II) (1/1), [HgBr(0.30)Cl(0.70)(C(12)H(19)N(2))]·[HgBr(0.24)Cl(0.76)(C(12)H(19)N(2))], there are two molecules in the asymmetric unit of formula LHgX {L = 2,6-bis[(dimethylamino)methyl]phenyl and X = Cl/Br}. In each molecule, the halide site is mixed Cl/Br, with occupancies of 0.699 (7):0.301 (7) and 0.763 (7):0.237 (7), respectively. The two molecules are linked into dimers by a combination of Hg⋯Hg [Hg⋯Hg = 3.6153 (3) Å] and C—H⋯Cl and C—H⋯π interactions. |
---|