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Crystal structure of {2,6-bis[(dimethylamino)methyl]phenyl-κ(3) N,C (1),N′}(bromido/chlorido)mercury(II)
In the molecular structure of the title compound, {2,6-bis[(dimethylamino)methyl]phenyl-κ(3) N,C (1),N′}[bromido/chlorido(0.30/0.70)]mercury(II)–{2,6-bis[(dimethylamino)methyl]phenyl-κ(3) N,C (1),N′}[bromido/chlorido(0.24/0.76)]mercury(II) (1/1), [HgBr(0.30)Cl(0.70)(C(12)H(19)N(2))]·[H...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683489/ https://www.ncbi.nlm.nih.gov/pubmed/29152349 http://dx.doi.org/10.1107/S2056989017014682 |
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author | Gupta, Anand Singh, Harkesh B. Butcher, Ray J. |
author_facet | Gupta, Anand Singh, Harkesh B. Butcher, Ray J. |
author_sort | Gupta, Anand |
collection | PubMed |
description | In the molecular structure of the title compound, {2,6-bis[(dimethylamino)methyl]phenyl-κ(3) N,C (1),N′}[bromido/chlorido(0.30/0.70)]mercury(II)–{2,6-bis[(dimethylamino)methyl]phenyl-κ(3) N,C (1),N′}[bromido/chlorido(0.24/0.76)]mercury(II) (1/1), [HgBr(0.30)Cl(0.70)(C(12)H(19)N(2))]·[HgBr(0.24)Cl(0.76)(C(12)H(19)N(2))], there are two molecules in the asymmetric unit of formula LHgX {L = 2,6-bis[(dimethylamino)methyl]phenyl and X = Cl/Br}. In each molecule, the halide site is mixed Cl/Br, with occupancies of 0.699 (7):0.301 (7) and 0.763 (7):0.237 (7), respectively. The two molecules are linked into dimers by a combination of Hg⋯Hg [Hg⋯Hg = 3.6153 (3) Å] and C—H⋯Cl and C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-5683489 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-56834892017-11-17 Crystal structure of {2,6-bis[(dimethylamino)methyl]phenyl-κ(3) N,C (1),N′}(bromido/chlorido)mercury(II) Gupta, Anand Singh, Harkesh B. Butcher, Ray J. Acta Crystallogr E Crystallogr Commun Research Communications In the molecular structure of the title compound, {2,6-bis[(dimethylamino)methyl]phenyl-κ(3) N,C (1),N′}[bromido/chlorido(0.30/0.70)]mercury(II)–{2,6-bis[(dimethylamino)methyl]phenyl-κ(3) N,C (1),N′}[bromido/chlorido(0.24/0.76)]mercury(II) (1/1), [HgBr(0.30)Cl(0.70)(C(12)H(19)N(2))]·[HgBr(0.24)Cl(0.76)(C(12)H(19)N(2))], there are two molecules in the asymmetric unit of formula LHgX {L = 2,6-bis[(dimethylamino)methyl]phenyl and X = Cl/Br}. In each molecule, the halide site is mixed Cl/Br, with occupancies of 0.699 (7):0.301 (7) and 0.763 (7):0.237 (7), respectively. The two molecules are linked into dimers by a combination of Hg⋯Hg [Hg⋯Hg = 3.6153 (3) Å] and C—H⋯Cl and C—H⋯π interactions. International Union of Crystallography 2017-10-20 /pmc/articles/PMC5683489/ /pubmed/29152349 http://dx.doi.org/10.1107/S2056989017014682 Text en © Gupta et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Gupta, Anand Singh, Harkesh B. Butcher, Ray J. Crystal structure of {2,6-bis[(dimethylamino)methyl]phenyl-κ(3) N,C (1),N′}(bromido/chlorido)mercury(II) |
title | Crystal structure of {2,6-bis[(dimethylamino)methyl]phenyl-κ(3)
N,C
(1),N′}(bromido/chlorido)mercury(II) |
title_full | Crystal structure of {2,6-bis[(dimethylamino)methyl]phenyl-κ(3)
N,C
(1),N′}(bromido/chlorido)mercury(II) |
title_fullStr | Crystal structure of {2,6-bis[(dimethylamino)methyl]phenyl-κ(3)
N,C
(1),N′}(bromido/chlorido)mercury(II) |
title_full_unstemmed | Crystal structure of {2,6-bis[(dimethylamino)methyl]phenyl-κ(3)
N,C
(1),N′}(bromido/chlorido)mercury(II) |
title_short | Crystal structure of {2,6-bis[(dimethylamino)methyl]phenyl-κ(3)
N,C
(1),N′}(bromido/chlorido)mercury(II) |
title_sort | crystal structure of {2,6-bis[(dimethylamino)methyl]phenyl-κ(3)
n,c
(1),n′}(bromido/chlorido)mercury(ii) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683489/ https://www.ncbi.nlm.nih.gov/pubmed/29152349 http://dx.doi.org/10.1107/S2056989017014682 |
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