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Synthesis and crystal structure of bis­(1H-benzo[d][1,2,3]triazole-κN (2)){2,2′-[N-(phenyl­phospho­r­yl­methyl-κO)aza­nedi­yl]di­acetato-κ(3) O,N,O′}cobalt(II)–1H-benzo[d][1,2,3]triazole (1/1)

In the title compound, [Co(C(11)H(12)NO(6)P)(C(6)H(5)N(3))(2)]·C(6)H(5)N(3), the 2,2′-[N-(phenyl­phospho­rylmethyl-κO)aza­nedi­yl]di­acetate dianion N,O,O′,O′′-chelates the Co(II) cation and two 1H-benzo[d][1,2,3]triazole mol­ecules coordinate to the Co(II) cation to complete the slightly distorted...

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Detalles Bibliográficos
Autores principales: Du, Chao-Jun, Zhao, Xiao-Na
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683495/
https://www.ncbi.nlm.nih.gov/pubmed/29152355
http://dx.doi.org/10.1107/S2056989017015079
Descripción
Sumario:In the title compound, [Co(C(11)H(12)NO(6)P)(C(6)H(5)N(3))(2)]·C(6)H(5)N(3), the 2,2′-[N-(phenyl­phospho­rylmethyl-κO)aza­nedi­yl]di­acetate dianion N,O,O′,O′′-chelates the Co(II) cation and two 1H-benzo[d][1,2,3]triazole mol­ecules coordinate to the Co(II) cation to complete the slightly distorted octa­hedral coordination. In the crystal, classical O—H⋯O, N—H⋯O hydrogen bonds and weak C—H⋯N hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular architecture. π–π stacking between the triazole and benzene rings and between the benzene rings is also observed in the crystal.