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Synthesis and crystal structure of bis(1H-benzo[d][1,2,3]triazole-κN (2)){2,2′-[N-(phenylphosphorylmethyl-κO)azanediyl]diacetato-κ(3) O,N,O′}cobalt(II)–1H-benzo[d][1,2,3]triazole (1/1)
In the title compound, [Co(C(11)H(12)NO(6)P)(C(6)H(5)N(3))(2)]·C(6)H(5)N(3), the 2,2′-[N-(phenylphosphorylmethyl-κO)azanediyl]diacetate dianion N,O,O′,O′′-chelates the Co(II) cation and two 1H-benzo[d][1,2,3]triazole molecules coordinate to the Co(II) cation to complete the slightly distorted...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683495/ https://www.ncbi.nlm.nih.gov/pubmed/29152355 http://dx.doi.org/10.1107/S2056989017015079 |
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author | Du, Chao-Jun Zhao, Xiao-Na |
author_facet | Du, Chao-Jun Zhao, Xiao-Na |
author_sort | Du, Chao-Jun |
collection | PubMed |
description | In the title compound, [Co(C(11)H(12)NO(6)P)(C(6)H(5)N(3))(2)]·C(6)H(5)N(3), the 2,2′-[N-(phenylphosphorylmethyl-κO)azanediyl]diacetate dianion N,O,O′,O′′-chelates the Co(II) cation and two 1H-benzo[d][1,2,3]triazole molecules coordinate to the Co(II) cation to complete the slightly distorted octahedral coordination. In the crystal, classical O—H⋯O, N—H⋯O hydrogen bonds and weak C—H⋯N hydrogen bonds link the molecules into a three-dimensional supramolecular architecture. π–π stacking between the triazole and benzene rings and between the benzene rings is also observed in the crystal. |
format | Online Article Text |
id | pubmed-5683495 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-56834952017-11-17 Synthesis and crystal structure of bis(1H-benzo[d][1,2,3]triazole-κN (2)){2,2′-[N-(phenylphosphorylmethyl-κO)azanediyl]diacetato-κ(3) O,N,O′}cobalt(II)–1H-benzo[d][1,2,3]triazole (1/1) Du, Chao-Jun Zhao, Xiao-Na Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Co(C(11)H(12)NO(6)P)(C(6)H(5)N(3))(2)]·C(6)H(5)N(3), the 2,2′-[N-(phenylphosphorylmethyl-κO)azanediyl]diacetate dianion N,O,O′,O′′-chelates the Co(II) cation and two 1H-benzo[d][1,2,3]triazole molecules coordinate to the Co(II) cation to complete the slightly distorted octahedral coordination. In the crystal, classical O—H⋯O, N—H⋯O hydrogen bonds and weak C—H⋯N hydrogen bonds link the molecules into a three-dimensional supramolecular architecture. π–π stacking between the triazole and benzene rings and between the benzene rings is also observed in the crystal. International Union of Crystallography 2017-10-20 /pmc/articles/PMC5683495/ /pubmed/29152355 http://dx.doi.org/10.1107/S2056989017015079 Text en © Du and Zhao 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Du, Chao-Jun Zhao, Xiao-Na Synthesis and crystal structure of bis(1H-benzo[d][1,2,3]triazole-κN (2)){2,2′-[N-(phenylphosphorylmethyl-κO)azanediyl]diacetato-κ(3) O,N,O′}cobalt(II)–1H-benzo[d][1,2,3]triazole (1/1) |
title | Synthesis and crystal structure of bis(1H-benzo[d][1,2,3]triazole-κN
(2)){2,2′-[N-(phenylphosphorylmethyl-κO)azanediyl]diacetato-κ(3)
O,N,O′}cobalt(II)–1H-benzo[d][1,2,3]triazole (1/1) |
title_full | Synthesis and crystal structure of bis(1H-benzo[d][1,2,3]triazole-κN
(2)){2,2′-[N-(phenylphosphorylmethyl-κO)azanediyl]diacetato-κ(3)
O,N,O′}cobalt(II)–1H-benzo[d][1,2,3]triazole (1/1) |
title_fullStr | Synthesis and crystal structure of bis(1H-benzo[d][1,2,3]triazole-κN
(2)){2,2′-[N-(phenylphosphorylmethyl-κO)azanediyl]diacetato-κ(3)
O,N,O′}cobalt(II)–1H-benzo[d][1,2,3]triazole (1/1) |
title_full_unstemmed | Synthesis and crystal structure of bis(1H-benzo[d][1,2,3]triazole-κN
(2)){2,2′-[N-(phenylphosphorylmethyl-κO)azanediyl]diacetato-κ(3)
O,N,O′}cobalt(II)–1H-benzo[d][1,2,3]triazole (1/1) |
title_short | Synthesis and crystal structure of bis(1H-benzo[d][1,2,3]triazole-κN
(2)){2,2′-[N-(phenylphosphorylmethyl-κO)azanediyl]diacetato-κ(3)
O,N,O′}cobalt(II)–1H-benzo[d][1,2,3]triazole (1/1) |
title_sort | synthesis and crystal structure of bis(1h-benzo[d][1,2,3]triazole-κn
(2)){2,2′-[n-(phenylphosphorylmethyl-κo)azanediyl]diacetato-κ(3)
o,n,o′}cobalt(ii)–1h-benzo[d][1,2,3]triazole (1/1) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683495/ https://www.ncbi.nlm.nih.gov/pubmed/29152355 http://dx.doi.org/10.1107/S2056989017015079 |
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