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Crystal structure of aqua(perchlorato)bis[μ-(E)-2-({[2-(pyridin-2-yl)ethyl]imino}methyl)phenolato-κ(4) N,N′,O:O]dicopper(II) perchlorate
The title compound, [Cu(2)(ClO(4))(C(14)H(13)N(2)O)(2)(H(2)O)]ClO(4), crystallizes as an unsymmetrical dinuclear cation bridged by the phenoxy O atoms with one Cu(II) atom coordinated by a water molecule and the other by a perchlorate anion, thus making both Cu(II) atoms five-coordinate, and with...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683496/ https://www.ncbi.nlm.nih.gov/pubmed/29152356 http://dx.doi.org/10.1107/S2056989017014694 |
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author | Okeke, Ugochukwu Gultneh, Yilma Butcher, Ray J. |
author_facet | Okeke, Ugochukwu Gultneh, Yilma Butcher, Ray J. |
author_sort | Okeke, Ugochukwu |
collection | PubMed |
description | The title compound, [Cu(2)(ClO(4))(C(14)H(13)N(2)O)(2)(H(2)O)]ClO(4), crystallizes as an unsymmetrical dinuclear cation bridged by the phenoxy O atoms with one Cu(II) atom coordinated by a water molecule and the other by a perchlorate anion, thus making both Cu(II) atoms five-coordinate, and with a further perchlorate anion present for charge balance. A long interaction [2.9893 (5) Å] between one of the two Cu(II) atoms and an O atom of the perchlorate counter-ion links the cations and anions into linear chains along the a-axis direction. In addition, the water H atoms link with the perchlorate counter-ion. These interactions, along with numerous C—H⋯O interactions between the tetrahedral perchlorate anions, link the ions into a complex three-dimensional array. One of the perchlorate anions is disordered over two conformations with occupancies of 0.586 (4) and 0.414 (4). |
format | Online Article Text |
id | pubmed-5683496 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-56834962017-11-17 Crystal structure of aqua(perchlorato)bis[μ-(E)-2-({[2-(pyridin-2-yl)ethyl]imino}methyl)phenolato-κ(4) N,N′,O:O]dicopper(II) perchlorate Okeke, Ugochukwu Gultneh, Yilma Butcher, Ray J. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [Cu(2)(ClO(4))(C(14)H(13)N(2)O)(2)(H(2)O)]ClO(4), crystallizes as an unsymmetrical dinuclear cation bridged by the phenoxy O atoms with one Cu(II) atom coordinated by a water molecule and the other by a perchlorate anion, thus making both Cu(II) atoms five-coordinate, and with a further perchlorate anion present for charge balance. A long interaction [2.9893 (5) Å] between one of the two Cu(II) atoms and an O atom of the perchlorate counter-ion links the cations and anions into linear chains along the a-axis direction. In addition, the water H atoms link with the perchlorate counter-ion. These interactions, along with numerous C—H⋯O interactions between the tetrahedral perchlorate anions, link the ions into a complex three-dimensional array. One of the perchlorate anions is disordered over two conformations with occupancies of 0.586 (4) and 0.414 (4). International Union of Crystallography 2017-10-20 /pmc/articles/PMC5683496/ /pubmed/29152356 http://dx.doi.org/10.1107/S2056989017014694 Text en © Okeke et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Okeke, Ugochukwu Gultneh, Yilma Butcher, Ray J. Crystal structure of aqua(perchlorato)bis[μ-(E)-2-({[2-(pyridin-2-yl)ethyl]imino}methyl)phenolato-κ(4) N,N′,O:O]dicopper(II) perchlorate |
title | Crystal structure of aqua(perchlorato)bis[μ-(E)-2-({[2-(pyridin-2-yl)ethyl]imino}methyl)phenolato-κ(4)
N,N′,O:O]dicopper(II) perchlorate |
title_full | Crystal structure of aqua(perchlorato)bis[μ-(E)-2-({[2-(pyridin-2-yl)ethyl]imino}methyl)phenolato-κ(4)
N,N′,O:O]dicopper(II) perchlorate |
title_fullStr | Crystal structure of aqua(perchlorato)bis[μ-(E)-2-({[2-(pyridin-2-yl)ethyl]imino}methyl)phenolato-κ(4)
N,N′,O:O]dicopper(II) perchlorate |
title_full_unstemmed | Crystal structure of aqua(perchlorato)bis[μ-(E)-2-({[2-(pyridin-2-yl)ethyl]imino}methyl)phenolato-κ(4)
N,N′,O:O]dicopper(II) perchlorate |
title_short | Crystal structure of aqua(perchlorato)bis[μ-(E)-2-({[2-(pyridin-2-yl)ethyl]imino}methyl)phenolato-κ(4)
N,N′,O:O]dicopper(II) perchlorate |
title_sort | crystal structure of aqua(perchlorato)bis[μ-(e)-2-({[2-(pyridin-2-yl)ethyl]imino}methyl)phenolato-κ(4)
n,n′,o:o]dicopper(ii) perchlorate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683496/ https://www.ncbi.nlm.nih.gov/pubmed/29152356 http://dx.doi.org/10.1107/S2056989017014694 |
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