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Crystal structure of aqua­(perchlorato)bis­[μ-(E)-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)phenolato-κ(4) N,N′,O:O]dicopper(II) perchlorate

The title compound, [Cu(2)(ClO(4))(C(14)H(13)N(2)O)(2)(H(2)O)]ClO(4), crystallizes as an unsymmetrical dinuclear cation bridged by the phen­oxy O atoms with one Cu(II) atom coordinated by a water mol­ecule and the other by a perchlorate anion, thus making both Cu(II) atoms five-coordinate, and with...

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Autores principales: Okeke, Ugochukwu, Gultneh, Yilma, Butcher, Ray J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683496/
https://www.ncbi.nlm.nih.gov/pubmed/29152356
http://dx.doi.org/10.1107/S2056989017014694
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author Okeke, Ugochukwu
Gultneh, Yilma
Butcher, Ray J.
author_facet Okeke, Ugochukwu
Gultneh, Yilma
Butcher, Ray J.
author_sort Okeke, Ugochukwu
collection PubMed
description The title compound, [Cu(2)(ClO(4))(C(14)H(13)N(2)O)(2)(H(2)O)]ClO(4), crystallizes as an unsymmetrical dinuclear cation bridged by the phen­oxy O atoms with one Cu(II) atom coordinated by a water mol­ecule and the other by a perchlorate anion, thus making both Cu(II) atoms five-coordinate, and with a further perchlorate anion present for charge balance. A long inter­action [2.9893 (5) Å] between one of the two Cu(II) atoms and an O atom of the perchlorate counter-ion links the cations and anions into linear chains along the a-axis direction. In addition, the water H atoms link with the perchlorate counter-ion. These inter­actions, along with numerous C—H⋯O inter­actions between the tetra­hedral perchlorate anions, link the ions into a complex three-dimensional array. One of the perchlorate anions is disordered over two conformations with occupancies of 0.586 (4) and 0.414 (4).
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spelling pubmed-56834962017-11-17 Crystal structure of aqua­(perchlorato)bis­[μ-(E)-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)phenolato-κ(4) N,N′,O:O]dicopper(II) perchlorate Okeke, Ugochukwu Gultneh, Yilma Butcher, Ray J. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [Cu(2)(ClO(4))(C(14)H(13)N(2)O)(2)(H(2)O)]ClO(4), crystallizes as an unsymmetrical dinuclear cation bridged by the phen­oxy O atoms with one Cu(II) atom coordinated by a water mol­ecule and the other by a perchlorate anion, thus making both Cu(II) atoms five-coordinate, and with a further perchlorate anion present for charge balance. A long inter­action [2.9893 (5) Å] between one of the two Cu(II) atoms and an O atom of the perchlorate counter-ion links the cations and anions into linear chains along the a-axis direction. In addition, the water H atoms link with the perchlorate counter-ion. These inter­actions, along with numerous C—H⋯O inter­actions between the tetra­hedral perchlorate anions, link the ions into a complex three-dimensional array. One of the perchlorate anions is disordered over two conformations with occupancies of 0.586 (4) and 0.414 (4). International Union of Crystallography 2017-10-20 /pmc/articles/PMC5683496/ /pubmed/29152356 http://dx.doi.org/10.1107/S2056989017014694 Text en © Okeke et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Okeke, Ugochukwu
Gultneh, Yilma
Butcher, Ray J.
Crystal structure of aqua­(perchlorato)bis­[μ-(E)-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)phenolato-κ(4) N,N′,O:O]dicopper(II) perchlorate
title Crystal structure of aqua­(perchlorato)bis­[μ-(E)-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)phenolato-κ(4) N,N′,O:O]dicopper(II) perchlorate
title_full Crystal structure of aqua­(perchlorato)bis­[μ-(E)-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)phenolato-κ(4) N,N′,O:O]dicopper(II) perchlorate
title_fullStr Crystal structure of aqua­(perchlorato)bis­[μ-(E)-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)phenolato-κ(4) N,N′,O:O]dicopper(II) perchlorate
title_full_unstemmed Crystal structure of aqua­(perchlorato)bis­[μ-(E)-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)phenolato-κ(4) N,N′,O:O]dicopper(II) perchlorate
title_short Crystal structure of aqua­(perchlorato)bis­[μ-(E)-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)phenolato-κ(4) N,N′,O:O]dicopper(II) perchlorate
title_sort crystal structure of aqua­(perchlorato)bis­[μ-(e)-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)phenolato-κ(4) n,n′,o:o]dicopper(ii) perchlorate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683496/
https://www.ncbi.nlm.nih.gov/pubmed/29152356
http://dx.doi.org/10.1107/S2056989017014694
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