Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabi­cyclo­[3.2.1]oct-3-yl)ammonium aqua­tri­chlorido­nitratocopper(II)

The structure of a salt of diprotonated endo-3-amino­tropane crystallized with a copper(II) anionic cluster is reported, viz. (C(8)H(18)N(2))[CuCl(3)(NO(3))(H(2)O)]. Neither ion in the salt has been structurally characterized previously. In the crystal, the ions pack together to form a three-dimensi...

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Detalles Bibliográficos
Autores principales: Britvin, Sergey N., Rumyantsev, Andrey M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683497/
https://www.ncbi.nlm.nih.gov/pubmed/29152357
http://dx.doi.org/10.1107/S2056989017014633
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author Britvin, Sergey N.
Rumyantsev, Andrey M.
author_facet Britvin, Sergey N.
Rumyantsev, Andrey M.
author_sort Britvin, Sergey N.
collection PubMed
description The structure of a salt of diprotonated endo-3-amino­tropane crystallized with a copper(II) anionic cluster is reported, viz. (C(8)H(18)N(2))[CuCl(3)(NO(3))(H(2)O)]. Neither ion in the salt has been structurally characterized previously. In the crystal, the ions pack together to form a three-dimensional structure held together by a network of inter­molecular N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen-bonding inter­actions. Selective crystallization of the title compound can be considered as a simple method for the separation of the exo and endo isomers of 3-amino­tropane.
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spelling pubmed-56834972017-11-17 Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabi­cyclo­[3.2.1]oct-3-yl)ammonium aqua­tri­chlorido­nitratocopper(II) Britvin, Sergey N. Rumyantsev, Andrey M. Acta Crystallogr E Crystallogr Commun Research Communications The structure of a salt of diprotonated endo-3-amino­tropane crystallized with a copper(II) anionic cluster is reported, viz. (C(8)H(18)N(2))[CuCl(3)(NO(3))(H(2)O)]. Neither ion in the salt has been structurally characterized previously. In the crystal, the ions pack together to form a three-dimensional structure held together by a network of inter­molecular N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen-bonding inter­actions. Selective crystallization of the title compound can be considered as a simple method for the separation of the exo and endo isomers of 3-amino­tropane. International Union of Crystallography 2017-10-20 /pmc/articles/PMC5683497/ /pubmed/29152357 http://dx.doi.org/10.1107/S2056989017014633 Text en © Britvin and Rumyantsev 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Britvin, Sergey N.
Rumyantsev, Andrey M.
Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabi­cyclo­[3.2.1]oct-3-yl)ammonium aqua­tri­chlorido­nitratocopper(II)
title Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabi­cyclo­[3.2.1]oct-3-yl)ammonium aqua­tri­chlorido­nitratocopper(II)
title_full Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabi­cyclo­[3.2.1]oct-3-yl)ammonium aqua­tri­chlorido­nitratocopper(II)
title_fullStr Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabi­cyclo­[3.2.1]oct-3-yl)ammonium aqua­tri­chlorido­nitratocopper(II)
title_full_unstemmed Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabi­cyclo­[3.2.1]oct-3-yl)ammonium aqua­tri­chlorido­nitratocopper(II)
title_short Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabi­cyclo­[3.2.1]oct-3-yl)ammonium aqua­tri­chlorido­nitratocopper(II)
title_sort crystal structure of (1r,5s)-endo-(8-methyl-8-azoniabi­cyclo­[3.2.1]oct-3-yl)ammonium aqua­tri­chlorido­nitratocopper(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683497/
https://www.ncbi.nlm.nih.gov/pubmed/29152357
http://dx.doi.org/10.1107/S2056989017014633
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