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4-Benzyl-1-(4-nitro­phen­yl)-1H-1,2,3-triazole: crystal structure and Hirshfeld analysis

The mol­ecule in the title compound, C(15)H(12)N(4)O(2), has a twisted L-shape with the dihedral angle between the aromatic rings of the N-bound benzene and C-bound benzyl groups being 70.60 (9)°. The nitro group is co-planar with the benzene ring to which it is connected [C—C—N—O torsion angle = 0....

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Detalles Bibliográficos
Autores principales: Zukerman-Schpector, Julio, Dallasta Pedroso, Sofia, Sousa Madureira, Lucas, Weber Paixão, Márcio, Ali, Akbar, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683498/
https://www.ncbi.nlm.nih.gov/pubmed/29152358
http://dx.doi.org/10.1107/S2056989017014748
Descripción
Sumario:The mol­ecule in the title compound, C(15)H(12)N(4)O(2), has a twisted L-shape with the dihedral angle between the aromatic rings of the N-bound benzene and C-bound benzyl groups being 70.60 (9)°. The nitro group is co-planar with the benzene ring to which it is connected [C—C—N—O torsion angle = 0.4 (3)°]. The three-dimensional packing is stabilized by a combination of methyl­ene-C—H⋯O(nitro), methyl­ene-C—H⋯π(phen­yl), phenyl-C—H⋯π(triazol­yl) and nitro-O⋯π(nitro­benzene) inter­actions, along with weak π(triazol­yl)–π(nitrobenzene) contacts [inter-centroid distance = 3.8386 (10) Å]. The importance of the specified inter­molecular contacts has been verified by an analysis of the calculated Hirshfeld surface.