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Crystal structure of 4,6-dimethyl-2-{[3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl]sulfanyl}nicotinonitrile
In the title compound, C(14)H(18)N(2)O(5)S, the C—S bond lengths are unequal, with S—C(glucose) = 1.8016 (15) Å and S—C(pyridyl) = 1.7723 (13) Å. The hydrophilic glucose residues lie in the regions z ≃ 0.25 and 0.75. Four classical hydrogen bonds link the molecules to form layers parallel to the...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683506/ https://www.ncbi.nlm.nih.gov/pubmed/29152366 http://dx.doi.org/10.1107/S2056989017015213 |
| _version_ | 1783278295893147648 |
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| author | Masoud, Doaa M. Hammad, Sherif F. Elgemeie, Galal H. Jones, Peter G. |
| author_facet | Masoud, Doaa M. Hammad, Sherif F. Elgemeie, Galal H. Jones, Peter G. |
| author_sort | Masoud, Doaa M. |
| collection | PubMed |
| description | In the title compound, C(14)H(18)N(2)O(5)S, the C—S bond lengths are unequal, with S—C(glucose) = 1.8016 (15) Å and S—C(pyridyl) = 1.7723 (13) Å. The hydrophilic glucose residues lie in the regions z ≃ 0.25 and 0.75. Four classical hydrogen bonds link the molecules to form layers parallel to the ab plane, from which the pyridyl rings project; pyridyl ring stacking parallel to the a axis links adjacent layers. |
| format | Online Article Text |
| id | pubmed-5683506 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2017 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-56835062017-11-17 Crystal structure of 4,6-dimethyl-2-{[3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl]sulfanyl}nicotinonitrile Masoud, Doaa M. Hammad, Sherif F. Elgemeie, Galal H. Jones, Peter G. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(14)H(18)N(2)O(5)S, the C—S bond lengths are unequal, with S—C(glucose) = 1.8016 (15) Å and S—C(pyridyl) = 1.7723 (13) Å. The hydrophilic glucose residues lie in the regions z ≃ 0.25 and 0.75. Four classical hydrogen bonds link the molecules to form layers parallel to the ab plane, from which the pyridyl rings project; pyridyl ring stacking parallel to the a axis links adjacent layers. International Union of Crystallography 2017-10-20 /pmc/articles/PMC5683506/ /pubmed/29152366 http://dx.doi.org/10.1107/S2056989017015213 Text en © Masoud et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
| spellingShingle | Research Communications Masoud, Doaa M. Hammad, Sherif F. Elgemeie, Galal H. Jones, Peter G. Crystal structure of 4,6-dimethyl-2-{[3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl]sulfanyl}nicotinonitrile |
| title | Crystal structure of 4,6-dimethyl-2-{[3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl]sulfanyl}nicotinonitrile |
| title_full | Crystal structure of 4,6-dimethyl-2-{[3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl]sulfanyl}nicotinonitrile |
| title_fullStr | Crystal structure of 4,6-dimethyl-2-{[3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl]sulfanyl}nicotinonitrile |
| title_full_unstemmed | Crystal structure of 4,6-dimethyl-2-{[3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl]sulfanyl}nicotinonitrile |
| title_short | Crystal structure of 4,6-dimethyl-2-{[3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl]sulfanyl}nicotinonitrile |
| title_sort | crystal structure of 4,6-dimethyl-2-{[3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2h-pyran-2-yl]sulfanyl}nicotinonitrile |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683506/ https://www.ncbi.nlm.nih.gov/pubmed/29152366 http://dx.doi.org/10.1107/S2056989017015213 |
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