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Crystal structure of poly[tetra-μ-cyanido-ethanolbis(2-iodopyrazine)digold(I)iron(II)]
In the title polymeric complex, [Au(2)Fe(CN)(4)(C(4)H(3)IN(2))(2)(C(2)H(6)O)](n), the Fe(II) cation is coordinated by two iodopyrazine molecules, one ethanol molecule and three dicyanoaurate anions in a distorted N(5)O octahedral geometry. In the crystal, the dicyanoaurate anions bridge the...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683507/ https://www.ncbi.nlm.nih.gov/pubmed/29152367 http://dx.doi.org/10.1107/S2056989017014785 |
| _version_ | 1783278296137465856 |
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| author | Fei, Bin Kucheriv, Olesia I. Tokmenko, Inna I. Terebilenko, Kateryna V. Gural’skiy, Il’ya A. |
| author_facet | Fei, Bin Kucheriv, Olesia I. Tokmenko, Inna I. Terebilenko, Kateryna V. Gural’skiy, Il’ya A. |
| author_sort | Fei, Bin |
| collection | PubMed |
| description | In the title polymeric complex, [Au(2)Fe(CN)(4)(C(4)H(3)IN(2))(2)(C(2)H(6)O)](n), the Fe(II) cation is coordinated by two iodopyrazine molecules, one ethanol molecule and three dicyanoaurate anions in a distorted N(5)O octahedral geometry. In the crystal, the dicyanoaurate anions bridge the Fe(II) cations to form polymeric chains propagating along the b-axis direction. Stabilization of the crystal structure is provided by O—H⋯N hydrogen bonds and π–π stacking between parallel iodopyrazine rings of neighbouring chains, the centroid–centroid distances being 3.654 (10) and 3.658 (9) Å. |
| format | Online Article Text |
| id | pubmed-5683507 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2017 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-56835072017-11-17 Crystal structure of poly[tetra-μ-cyanido-ethanolbis(2-iodopyrazine)digold(I)iron(II)] Fei, Bin Kucheriv, Olesia I. Tokmenko, Inna I. Terebilenko, Kateryna V. Gural’skiy, Il’ya A. Acta Crystallogr E Crystallogr Commun Research Communications In the title polymeric complex, [Au(2)Fe(CN)(4)(C(4)H(3)IN(2))(2)(C(2)H(6)O)](n), the Fe(II) cation is coordinated by two iodopyrazine molecules, one ethanol molecule and three dicyanoaurate anions in a distorted N(5)O octahedral geometry. In the crystal, the dicyanoaurate anions bridge the Fe(II) cations to form polymeric chains propagating along the b-axis direction. Stabilization of the crystal structure is provided by O—H⋯N hydrogen bonds and π–π stacking between parallel iodopyrazine rings of neighbouring chains, the centroid–centroid distances being 3.654 (10) and 3.658 (9) Å. International Union of Crystallography 2017-10-24 /pmc/articles/PMC5683507/ /pubmed/29152367 http://dx.doi.org/10.1107/S2056989017014785 Text en © Fei et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
| spellingShingle | Research Communications Fei, Bin Kucheriv, Olesia I. Tokmenko, Inna I. Terebilenko, Kateryna V. Gural’skiy, Il’ya A. Crystal structure of poly[tetra-μ-cyanido-ethanolbis(2-iodopyrazine)digold(I)iron(II)] |
| title | Crystal structure of poly[tetra-μ-cyanido-ethanolbis(2-iodopyrazine)digold(I)iron(II)] |
| title_full | Crystal structure of poly[tetra-μ-cyanido-ethanolbis(2-iodopyrazine)digold(I)iron(II)] |
| title_fullStr | Crystal structure of poly[tetra-μ-cyanido-ethanolbis(2-iodopyrazine)digold(I)iron(II)] |
| title_full_unstemmed | Crystal structure of poly[tetra-μ-cyanido-ethanolbis(2-iodopyrazine)digold(I)iron(II)] |
| title_short | Crystal structure of poly[tetra-μ-cyanido-ethanolbis(2-iodopyrazine)digold(I)iron(II)] |
| title_sort | crystal structure of poly[tetra-μ-cyanido-ethanolbis(2-iodopyrazine)digold(i)iron(ii)] |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683507/ https://www.ncbi.nlm.nih.gov/pubmed/29152367 http://dx.doi.org/10.1107/S2056989017014785 |
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