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Crystal structure of diethyl 3,3′-[(2-fluorophenyl)methylidene]bis(1H-indole-2-carboxylate)
In the title compound, C(29)H(25)FN(2)O(4), the mean planes of the two indole ring systems (r.m.s. deviations = 0.1392 and 0.0115 Å) are approximately perpendicular to one another, subtending a dihedral angle of 86.0 (5)°; the benzene ring is twisted with respect to the mean planes of the two indole...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683515/ https://www.ncbi.nlm.nih.gov/pubmed/29152375 http://dx.doi.org/10.1107/S2056989017015523 |
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author | Lu, Xin-Hua Sun, Hong-Shun Cai, Yuan Chen, Lu-Lu Chen, Yang-Feng |
author_facet | Lu, Xin-Hua Sun, Hong-Shun Cai, Yuan Chen, Lu-Lu Chen, Yang-Feng |
author_sort | Lu, Xin-Hua |
collection | PubMed |
description | In the title compound, C(29)H(25)FN(2)O(4), the mean planes of the two indole ring systems (r.m.s. deviations = 0.1392 and 0.0115 Å) are approximately perpendicular to one another, subtending a dihedral angle of 86.0 (5)°; the benzene ring is twisted with respect to the mean planes of the two indole ring systems by 83.3 (2) and 88.1 (4)°, respectively. In the crystal, pairs of N—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers, which are further linked by N—H⋯O hydrogen bonds into supramolecular chains propagating along the [101] direction. |
format | Online Article Text |
id | pubmed-5683515 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-56835152017-11-17 Crystal structure of diethyl 3,3′-[(2-fluorophenyl)methylidene]bis(1H-indole-2-carboxylate) Lu, Xin-Hua Sun, Hong-Shun Cai, Yuan Chen, Lu-Lu Chen, Yang-Feng Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(29)H(25)FN(2)O(4), the mean planes of the two indole ring systems (r.m.s. deviations = 0.1392 and 0.0115 Å) are approximately perpendicular to one another, subtending a dihedral angle of 86.0 (5)°; the benzene ring is twisted with respect to the mean planes of the two indole ring systems by 83.3 (2) and 88.1 (4)°, respectively. In the crystal, pairs of N—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers, which are further linked by N—H⋯O hydrogen bonds into supramolecular chains propagating along the [101] direction. International Union of Crystallography 2017-10-31 /pmc/articles/PMC5683515/ /pubmed/29152375 http://dx.doi.org/10.1107/S2056989017015523 Text en © Lu et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Lu, Xin-Hua Sun, Hong-Shun Cai, Yuan Chen, Lu-Lu Chen, Yang-Feng Crystal structure of diethyl 3,3′-[(2-fluorophenyl)methylidene]bis(1H-indole-2-carboxylate) |
title | Crystal structure of diethyl 3,3′-[(2-fluorophenyl)methylidene]bis(1H-indole-2-carboxylate) |
title_full | Crystal structure of diethyl 3,3′-[(2-fluorophenyl)methylidene]bis(1H-indole-2-carboxylate) |
title_fullStr | Crystal structure of diethyl 3,3′-[(2-fluorophenyl)methylidene]bis(1H-indole-2-carboxylate) |
title_full_unstemmed | Crystal structure of diethyl 3,3′-[(2-fluorophenyl)methylidene]bis(1H-indole-2-carboxylate) |
title_short | Crystal structure of diethyl 3,3′-[(2-fluorophenyl)methylidene]bis(1H-indole-2-carboxylate) |
title_sort | crystal structure of diethyl 3,3′-[(2-fluorophenyl)methylidene]bis(1h-indole-2-carboxylate) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683515/ https://www.ncbi.nlm.nih.gov/pubmed/29152375 http://dx.doi.org/10.1107/S2056989017015523 |
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