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Crystal structure of 2,3,5,6-tetra­kis­(pyridin-2-yl)pyrazine hydrogen peroxide 4.75-solvate

The structure of the title co-crystal, C(24)H(16)N(6)·4.75H(2)O(2), consists of a 2,3,5,6-tetra­kis­(pyridin-2-yl)pyrazine coformer and hydrogen peroxide solvent mol­ecules in an overall ratio of 1:4.75. Three of the six H(2)O(2) mol­ecules modelled in the structure were found to be cross-orientatio...

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Detalles Bibliográficos
Autores principales: Navasardyan, Mger A., Bezzubov, Stanislav I., Kuz’mina, Lyudmila G., Prikhodchenko, Petr V., Churakov, Andrei V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683516/
https://www.ncbi.nlm.nih.gov/pubmed/29152376
http://dx.doi.org/10.1107/S2056989017015328
Descripción
Sumario:The structure of the title co-crystal, C(24)H(16)N(6)·4.75H(2)O(2), consists of a 2,3,5,6-tetra­kis­(pyridin-2-yl)pyrazine coformer and hydrogen peroxide solvent mol­ecules in an overall ratio of 1:4.75. Three of the six H(2)O(2) mol­ecules modelled in the structure were found to be cross-orientationally disordered over two positions with occupancy ratios 0.846 (9):0.154 (9), 0.75 (2):0.25 (2), and 0.891 (9):0.109 (9). In the crystal, all of the peroxide mol­ecules are linked into hydrogen-bonded chains that propagate parallel to the a axis. These chains are further linked by O—H⋯N hydrogen bonds to the pyridine groups of the main mol­ecule.