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Mild sp(2)Carbon–Oxygen Bond Activation by an Isolable Ruthenium(II) Bis(dinitrogen) Complex: Experiment and Theory

[Image: see text] The isolable ruthenium(II) bis(dinitrogen) complex [Ru(H)(2)(N(2))(2)(PCy(3))(2)] (1) reacts with aryl ethers (Ar–OR, R = Me and Ar) containing a ketone directing group to effect sp(2)C–O bond activation at temperatures below 40 °C. DFT studies support a low-energy Ru(II)/Ru(IV) pa...

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Detalles Bibliográficos
Autores principales:	Lau, Samantha, Ward, Bryan, Zhou, Xueer, White, Andrew J. P., Casely, Ian J., Macgregor, Stuart A., Crimmin, Mark R.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2017
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5684690/ https://www.ncbi.nlm.nih.gov/pubmed/29151664 http://dx.doi.org/10.1021/acs.organomet.7b00632

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