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Single-Site Photocatalytic H(2) Evolution from Covalent Organic Frameworks with Molecular Cobaloxime Co-Catalysts

[Image: see text] We demonstrate photocatalytic hydrogen evolution using COF photosensitizers with molecular proton reduction catalysts for the first time. With azine-linked N2-COF photosensitizer, chloro(pyridine)cobaloxime co-catalyst, and TEOA donor, H(2) evolution rate of 782 μmol h(–1) g(–1) an...

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Detalles Bibliográficos
Autores principales:	Banerjee, Tanmay, Haase, Frederik, Savasci, Gökcen, Gottschling, Kerstin, Ochsenfeld, Christian, Lotsch, Bettina V.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2017
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5691321/ https://www.ncbi.nlm.nih.gov/pubmed/29022345 http://dx.doi.org/10.1021/jacs.7b07489

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