Nb(2)©Au(6): a molecular wheel with a short Nb[triple bond, length as m-dash]Nb triple bond coordinated by an Au(6) ring and reinforced by σ aromaticity

We report a photoelectron spectroscopy and high-resolution photoelectron imaging study of a bimetallic Nb(2)Au(6)(–) cluster. Theoretical calculations, in conjunction with the experimental data, reveal that Nb(2)Au(6)(–/0) possess high-symmetry D(6h) structures featuring a Nb–Nb axis coordinated equ...

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Detalles Bibliográficos
Autores principales: Jian, Tian, Cheung, Ling Fung, Czekner, Joseph, Chen, Teng-Teng, Lopez, Gary V., Li, Wei-Li, Wang, Lai-Sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5694916/
https://www.ncbi.nlm.nih.gov/pubmed/29163907
http://dx.doi.org/10.1039/c7sc02881d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5694916/
https://www.ncbi.nlm.nih.gov/pubmed/29163907
http://dx.doi.org/10.1039/c7sc02881d

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