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Covalent Co–O–V and Sb–N Bonds Enable Polyoxovanadate Charge Control

[Image: see text] The formation of [{Co(II)(teta)(2)}{Co(II)(2)(tren)(teta)(2)}V(IV)(15)Sb(III)(6)O(42)(H(2)O)]·ca.9H(2)O [teta = triethylenetetraamine; tren = tris(2-aminoethyl)amine] illustrates a strategy toward reducing the molecular charge of polyoxovanadates, a key challenge in their use as co...

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Detalles Bibliográficos
Autores principales: Rasmussen, Maren, Näther, Christian, van Leusen, Jan, Kögerler, Paul, Zhechkov, Lyuben, Heine, Thoma, Bensch, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5696651/
https://www.ncbi.nlm.nih.gov/pubmed/28541697
http://dx.doi.org/10.1021/acs.inorgchem.7b00724

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