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Axially Symmetric U−O−Ln‐ and U−O−U‐Containing Molecules from the Control of Uranyl Reduction with Simple f‐Block Halides
The reduction of U(VI) uranyl halides or amides with simple Ln(II) or U(III) salts forms highly symmetric, linear, oxo‐bridged trinuclear U(V)/Ln(III)/U(V), Ln(III)/U(IV)/Ln(III), and U(IV)/U(IV)/U(IV) complexes or linear Ln(III)/U(V) polymers depending on the stoichiometry and solvent. The reaction...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5697649/ https://www.ncbi.nlm.nih.gov/pubmed/28686336 http://dx.doi.org/10.1002/anie.201705197 |