Gold(I)‐Catalyzed Synthesis of Indenes and Cyclopentadienes: Access to (±)‐Laurokamurene B and the Skeletons of the Cycloaurenones and Dysiherbols

The formal (3+2) cycloaddition between terminal allenes and aryl or styryl gold(I) carbenes generated by a retro‐Buchner reaction of 7‐substituted 1,3,5‐cycloheptatrienes led to indenes and cyclopentadienes, respectively. These cycloaddition processes have been applied to the construction of the car...

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Detalles Bibliográficos
Autores principales: Yin, Xiang, Mato, Mauro, Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5698700/
https://www.ncbi.nlm.nih.gov/pubmed/28941059
http://dx.doi.org/10.1002/anie.201708947
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author Yin, Xiang
Mato, Mauro
Echavarren, Antonio M.
author_facet Yin, Xiang
Mato, Mauro
Echavarren, Antonio M.
author_sort Yin, Xiang
collection PubMed
description The formal (3+2) cycloaddition between terminal allenes and aryl or styryl gold(I) carbenes generated by a retro‐Buchner reaction of 7‐substituted 1,3,5‐cycloheptatrienes led to indenes and cyclopentadienes, respectively. These cycloaddition processes have been applied to the construction of the carbon skeleton of the cycloaurenones and the dysiherbols as well as to the total synthesis of (±)‐laurokamurene B.
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spelling pubmed-56987002017-11-28 Gold(I)‐Catalyzed Synthesis of Indenes and Cyclopentadienes: Access to (±)‐Laurokamurene B and the Skeletons of the Cycloaurenones and Dysiherbols Yin, Xiang Mato, Mauro Echavarren, Antonio M. Angew Chem Int Ed Engl Communications The formal (3+2) cycloaddition between terminal allenes and aryl or styryl gold(I) carbenes generated by a retro‐Buchner reaction of 7‐substituted 1,3,5‐cycloheptatrienes led to indenes and cyclopentadienes, respectively. These cycloaddition processes have been applied to the construction of the carbon skeleton of the cycloaurenones and the dysiherbols as well as to the total synthesis of (±)‐laurokamurene B. John Wiley and Sons Inc. 2017-10-11 2017-11-13 /pmc/articles/PMC5698700/ /pubmed/28941059 http://dx.doi.org/10.1002/anie.201708947 Text en © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial (http://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Communications
Yin, Xiang
Mato, Mauro
Echavarren, Antonio M.
Gold(I)‐Catalyzed Synthesis of Indenes and Cyclopentadienes: Access to (±)‐Laurokamurene B and the Skeletons of the Cycloaurenones and Dysiherbols
title Gold(I)‐Catalyzed Synthesis of Indenes and Cyclopentadienes: Access to (±)‐Laurokamurene B and the Skeletons of the Cycloaurenones and Dysiherbols
title_full Gold(I)‐Catalyzed Synthesis of Indenes and Cyclopentadienes: Access to (±)‐Laurokamurene B and the Skeletons of the Cycloaurenones and Dysiherbols
title_fullStr Gold(I)‐Catalyzed Synthesis of Indenes and Cyclopentadienes: Access to (±)‐Laurokamurene B and the Skeletons of the Cycloaurenones and Dysiherbols
title_full_unstemmed Gold(I)‐Catalyzed Synthesis of Indenes and Cyclopentadienes: Access to (±)‐Laurokamurene B and the Skeletons of the Cycloaurenones and Dysiherbols
title_short Gold(I)‐Catalyzed Synthesis of Indenes and Cyclopentadienes: Access to (±)‐Laurokamurene B and the Skeletons of the Cycloaurenones and Dysiherbols
title_sort gold(i)‐catalyzed synthesis of indenes and cyclopentadienes: access to (±)‐laurokamurene b and the skeletons of the cycloaurenones and dysiherbols
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5698700/
https://www.ncbi.nlm.nih.gov/pubmed/28941059
http://dx.doi.org/10.1002/anie.201708947
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