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Gold(III) Alkyne Complexes: Bonding and Reaction Pathways

The synthesis and characterization of hitherto hypothetical Au(III) π‐alkyne complexes is reported. Bonding and stability depend strongly on the trans effect and steric factors. Bonding characteristics shed light on the reasons for the very different stabilities between the classical alkyne complexe...

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Detalles Bibliográficos
Autores principales:	Rocchigiani, Luca, Fernandez‐Cestau, Julio, Agonigi, Gabriele, Chambrier, Isabelle, Budzelaar, Peter H. M., Bochmann, Manfred
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2017
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5698712/ https://www.ncbi.nlm.nih.gov/pubmed/28892244 http://dx.doi.org/10.1002/anie.201708640

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