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Singlet oxygen-mediated selective C–H bond hydroperoxidation of ethereal hydrocarbons
Singlet O(2) is a key reactive oxygen species responsible for photodynamic therapy and is generally recognized to be chemically reactive towards C=C double bonds. Herein, we report the hydroperoxidation/lactonization of α-ethereal C–H bonds by singlet O(2) ((1)Δ(g)) under exceptionally mild conditio...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5703888/ https://www.ncbi.nlm.nih.gov/pubmed/29180784 http://dx.doi.org/10.1038/s41467-017-01906-5 |