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Catalytic Methane Monofunctionalization by an Electrogenerated High-Valent Pd Intermediate

[Image: see text] Electrophilic high-valent metal ions are potent intermediates for the catalytic functionalization of methane, but in many cases, their high redox potentials make these intermediates difficult or impossible to access using mild stoichiometric oxidants derived from O(2). Herein, we e...

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Detalles Bibliográficos
Autores principales: O’Reilly, Matthew E., Kim, R. Soyoung, Oh, Seokjoon, Surendranath, Yogesh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5704285/
https://www.ncbi.nlm.nih.gov/pubmed/29202019
http://dx.doi.org/10.1021/acscentsci.7b00342