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Catalytic Methane Monofunctionalization by an Electrogenerated High-Valent Pd Intermediate
[Image: see text] Electrophilic high-valent metal ions are potent intermediates for the catalytic functionalization of methane, but in many cases, their high redox potentials make these intermediates difficult or impossible to access using mild stoichiometric oxidants derived from O(2). Herein, we e...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5704285/ https://www.ncbi.nlm.nih.gov/pubmed/29202019 http://dx.doi.org/10.1021/acscentsci.7b00342 |