Syntheses, structures, and stabilities of aliphatic and aromatic fluorous iodine(I) and iodine(III) compounds: the role of iodine Lewis basicity

The title molecules are sought in connection with various synthetic applications. The aliphatic fluorous alcohols R(f)(n)CH(2)OH (R(f)(n) = CF(3)(CF(2))(n)(–1); n = 11, 13, 15) are converted to the triflates R(f)(n)CH(2)OTf (Tf(2)O, pyridine; 22–61%) and then to R(f)(n)CH(2)I (NaI, acetone; 58–69%)....

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Detalles Bibliográficos
Autores principales: Mukherjee, Tathagata, Biswas, Soumik, Ehnbom, Andreas, Ghosh, Subrata K, El-Zoghbi, Ibrahim, Bhuvanesh, Nattamai, Bazzi, Hassan S, Gladysz, John A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2017
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5704765/
https://www.ncbi.nlm.nih.gov/pubmed/29234476
http://dx.doi.org/10.3762/bjoc.13.246

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