Transformation of Organostannanes Based on Photocleavage of C-Sn Bond via Single Electron Transfer Process

In this work, we developed a new method for the transformation of organostannanes via radical process. In this reaction, highly reactive carbon radical species can be efficiently generated through HBr-catalyzed photocleavage of C-Sn bond via single electron transfer process. Under aerobic conditions...

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Autores principales: Li, Han, Jin, Ruiwen, Li, Yawei, Ding, Aishun, Hao, Xinqi, Guo, Hao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707384/
https://www.ncbi.nlm.nih.gov/pubmed/29185469
http://dx.doi.org/10.1038/s41598-017-16806-3
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author Li, Han
Jin, Ruiwen
Li, Yawei
Ding, Aishun
Hao, Xinqi
Guo, Hao
author_facet Li, Han
Jin, Ruiwen
Li, Yawei
Ding, Aishun
Hao, Xinqi
Guo, Hao
author_sort Li, Han
collection PubMed
description In this work, we developed a new method for the transformation of organostannanes via radical process. In this reaction, highly reactive carbon radical species can be efficiently generated through HBr-catalyzed photocleavage of C-Sn bond via single electron transfer process. Under aerobic conditions, the in situ formed primary/secondary alkyl radicals can be further highly selectively oxidized into carboxylic acids/ketones, respectively.
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spelling pubmed-57073842017-12-06 Transformation of Organostannanes Based on Photocleavage of C-Sn Bond via Single Electron Transfer Process Li, Han Jin, Ruiwen Li, Yawei Ding, Aishun Hao, Xinqi Guo, Hao Sci Rep Article In this work, we developed a new method for the transformation of organostannanes via radical process. In this reaction, highly reactive carbon radical species can be efficiently generated through HBr-catalyzed photocleavage of C-Sn bond via single electron transfer process. Under aerobic conditions, the in situ formed primary/secondary alkyl radicals can be further highly selectively oxidized into carboxylic acids/ketones, respectively. Nature Publishing Group UK 2017-11-29 /pmc/articles/PMC5707384/ /pubmed/29185469 http://dx.doi.org/10.1038/s41598-017-16806-3 Text en © The Author(s) 2017 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Li, Han
Jin, Ruiwen
Li, Yawei
Ding, Aishun
Hao, Xinqi
Guo, Hao
Transformation of Organostannanes Based on Photocleavage of C-Sn Bond via Single Electron Transfer Process
title Transformation of Organostannanes Based on Photocleavage of C-Sn Bond via Single Electron Transfer Process
title_full Transformation of Organostannanes Based on Photocleavage of C-Sn Bond via Single Electron Transfer Process
title_fullStr Transformation of Organostannanes Based on Photocleavage of C-Sn Bond via Single Electron Transfer Process
title_full_unstemmed Transformation of Organostannanes Based on Photocleavage of C-Sn Bond via Single Electron Transfer Process
title_short Transformation of Organostannanes Based on Photocleavage of C-Sn Bond via Single Electron Transfer Process
title_sort transformation of organostannanes based on photocleavage of c-sn bond via single electron transfer process
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707384/
https://www.ncbi.nlm.nih.gov/pubmed/29185469
http://dx.doi.org/10.1038/s41598-017-16806-3
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