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Investigating pyridazine and phthalazine exchange in a series of iridium complexes in order to define their role in the catalytic transfer of magnetisation from para-hydrogen

The reaction of [Ir(IMes)(COD)Cl], [IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene, COD = 1,5-cyclooctadiene] with pyridazine (pdz) and phthalazine (phth) results in the formation of [Ir(COD)(IMes)(pdz)]Cl and [Ir(COD)(IMes)(phth)]Cl. These two complexes are shown by nuclear magnetic resona...

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Detalles Bibliográficos
Autores principales: Appleby, Kate M., Mewis, Ryan E., Olaru, Alexandra M., Green, Gary G. R., Fairlamb, Ian J. S., Duckett, Simon B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707471/
https://www.ncbi.nlm.nih.gov/pubmed/29218168
http://dx.doi.org/10.1039/c5sc00756a