Homochiral self-assembly of biocoordination polymers: anion-triggered helicity and absolute configuration inversion

The different natures of the weakly coordinating anions – triflate or perchlorate – in the Cu(2+)-mediated self-assembly of cytidine monophosphate nucleotide play a fundamental role in the homochiral resolution process, yielding one-dimensional copper(ii) coordination polymers of opposite helicity t...

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Detalles Bibliográficos
Autores principales: Marino, Nadia, Armentano, Donatella, Pardo, Emilio, Vallejo, Julia, Neve, Francesco, Di Donna, Leonardo, De Munno, Giovanni
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707485/
https://www.ncbi.nlm.nih.gov/pubmed/29218199
http://dx.doi.org/10.1039/c5sc01089f
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author Marino, Nadia
Armentano, Donatella
Pardo, Emilio
Vallejo, Julia
Neve, Francesco
Di Donna, Leonardo
De Munno, Giovanni
author_facet Marino, Nadia
Armentano, Donatella
Pardo, Emilio
Vallejo, Julia
Neve, Francesco
Di Donna, Leonardo
De Munno, Giovanni
author_sort Marino, Nadia
collection PubMed
description The different natures of the weakly coordinating anions – triflate or perchlorate – in the Cu(2+)-mediated self-assembly of cytidine monophosphate nucleotide play a fundamental role in the homochiral resolution process, yielding one-dimensional copper(ii) coordination polymers of opposite helicity that can be easily inverted, in a reversible way, by changing the nature of the anion as revealed by circular dichroism experiments both in solution and in the solid state.
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spelling pubmed-57074852017-12-07 Homochiral self-assembly of biocoordination polymers: anion-triggered helicity and absolute configuration inversion Marino, Nadia Armentano, Donatella Pardo, Emilio Vallejo, Julia Neve, Francesco Di Donna, Leonardo De Munno, Giovanni Chem Sci Chemistry The different natures of the weakly coordinating anions – triflate or perchlorate – in the Cu(2+)-mediated self-assembly of cytidine monophosphate nucleotide play a fundamental role in the homochiral resolution process, yielding one-dimensional copper(ii) coordination polymers of opposite helicity that can be easily inverted, in a reversible way, by changing the nature of the anion as revealed by circular dichroism experiments both in solution and in the solid state. Royal Society of Chemistry 2015-07-01 2015-04-30 /pmc/articles/PMC5707485/ /pubmed/29218199 http://dx.doi.org/10.1039/c5sc01089f Text en This journal is © The Royal Society of Chemistry 2015 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Marino, Nadia
Armentano, Donatella
Pardo, Emilio
Vallejo, Julia
Neve, Francesco
Di Donna, Leonardo
De Munno, Giovanni
Homochiral self-assembly of biocoordination polymers: anion-triggered helicity and absolute configuration inversion
title Homochiral self-assembly of biocoordination polymers: anion-triggered helicity and absolute configuration inversion
title_full Homochiral self-assembly of biocoordination polymers: anion-triggered helicity and absolute configuration inversion
title_fullStr Homochiral self-assembly of biocoordination polymers: anion-triggered helicity and absolute configuration inversion
title_full_unstemmed Homochiral self-assembly of biocoordination polymers: anion-triggered helicity and absolute configuration inversion
title_short Homochiral self-assembly of biocoordination polymers: anion-triggered helicity and absolute configuration inversion
title_sort homochiral self-assembly of biocoordination polymers: anion-triggered helicity and absolute configuration inversion
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707485/
https://www.ncbi.nlm.nih.gov/pubmed/29218199
http://dx.doi.org/10.1039/c5sc01089f
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