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Homochiral self-assembly of biocoordination polymers: anion-triggered helicity and absolute configuration inversion
The different natures of the weakly coordinating anions – triflate or perchlorate – in the Cu(2+)-mediated self-assembly of cytidine monophosphate nucleotide play a fundamental role in the homochiral resolution process, yielding one-dimensional copper(ii) coordination polymers of opposite helicity t...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707485/ https://www.ncbi.nlm.nih.gov/pubmed/29218199 http://dx.doi.org/10.1039/c5sc01089f |