A single crystalline porphyrinic titanium metal–organic framework

We successfully assembled the photocatalytic titanium-oxo cluster and photosensitizing porphyrinic linker into a metal–organic framework (MOF), namely PCN-22. A preformed titanium-oxo carboxylate cluster is adopted as the starting material to judiciously control the MOF growth process to afford sing...

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Detalles Bibliográficos
Autores principales: Yuan, Shuai, Liu, Tian-Fu, Feng, Dawei, Tian, Jian, Wang, Kecheng, Qin, Junsheng, Zhang, Qiang, Chen, Ying-Pin, Bosch, Mathieu, Zou, Lanfang, Teat, Simon J., Dalgarno, Scott J., Zhou, Hong-Cai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707486/
https://www.ncbi.nlm.nih.gov/pubmed/29218163
http://dx.doi.org/10.1039/c5sc00916b
Descripción
Sumario:We successfully assembled the photocatalytic titanium-oxo cluster and photosensitizing porphyrinic linker into a metal–organic framework (MOF), namely PCN-22. A preformed titanium-oxo carboxylate cluster is adopted as the starting material to judiciously control the MOF growth process to afford single crystals. This synthetic method is useful to obtain highly crystalline titanium MOFs, which has been a daunting challenge in this field. Moreover, PCN-22 demonstrated permanent porosity and photocatalytic activities toward alcohol oxidation.

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