A single crystalline porphyrinic titanium metal–organic framework

We successfully assembled the photocatalytic titanium-oxo cluster and photosensitizing porphyrinic linker into a metal–organic framework (MOF), namely PCN-22. A preformed titanium-oxo carboxylate cluster is adopted as the starting material to judiciously control the MOF growth process to afford sing...

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Detalles Bibliográficos
Autores principales: Yuan, Shuai, Liu, Tian-Fu, Feng, Dawei, Tian, Jian, Wang, Kecheng, Qin, Junsheng, Zhang, Qiang, Chen, Ying-Pin, Bosch, Mathieu, Zou, Lanfang, Teat, Simon J., Dalgarno, Scott J., Zhou, Hong-Cai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707486/
https://www.ncbi.nlm.nih.gov/pubmed/29218163
http://dx.doi.org/10.1039/c5sc00916b
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author Yuan, Shuai
Liu, Tian-Fu
Feng, Dawei
Tian, Jian
Wang, Kecheng
Qin, Junsheng
Zhang, Qiang
Chen, Ying-Pin
Bosch, Mathieu
Zou, Lanfang
Teat, Simon J.
Dalgarno, Scott J.
Zhou, Hong-Cai
author_facet Yuan, Shuai
Liu, Tian-Fu
Feng, Dawei
Tian, Jian
Wang, Kecheng
Qin, Junsheng
Zhang, Qiang
Chen, Ying-Pin
Bosch, Mathieu
Zou, Lanfang
Teat, Simon J.
Dalgarno, Scott J.
Zhou, Hong-Cai
author_sort Yuan, Shuai
collection PubMed
description We successfully assembled the photocatalytic titanium-oxo cluster and photosensitizing porphyrinic linker into a metal–organic framework (MOF), namely PCN-22. A preformed titanium-oxo carboxylate cluster is adopted as the starting material to judiciously control the MOF growth process to afford single crystals. This synthetic method is useful to obtain highly crystalline titanium MOFs, which has been a daunting challenge in this field. Moreover, PCN-22 demonstrated permanent porosity and photocatalytic activities toward alcohol oxidation.
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spelling pubmed-57074862017-12-07 A single crystalline porphyrinic titanium metal–organic framework Yuan, Shuai Liu, Tian-Fu Feng, Dawei Tian, Jian Wang, Kecheng Qin, Junsheng Zhang, Qiang Chen, Ying-Pin Bosch, Mathieu Zou, Lanfang Teat, Simon J. Dalgarno, Scott J. Zhou, Hong-Cai Chem Sci Chemistry We successfully assembled the photocatalytic titanium-oxo cluster and photosensitizing porphyrinic linker into a metal–organic framework (MOF), namely PCN-22. A preformed titanium-oxo carboxylate cluster is adopted as the starting material to judiciously control the MOF growth process to afford single crystals. This synthetic method is useful to obtain highly crystalline titanium MOFs, which has been a daunting challenge in this field. Moreover, PCN-22 demonstrated permanent porosity and photocatalytic activities toward alcohol oxidation. Royal Society of Chemistry 2015-07-01 2015-04-28 /pmc/articles/PMC5707486/ /pubmed/29218163 http://dx.doi.org/10.1039/c5sc00916b Text en This journal is © The Royal Society of Chemistry 2015 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Yuan, Shuai
Liu, Tian-Fu
Feng, Dawei
Tian, Jian
Wang, Kecheng
Qin, Junsheng
Zhang, Qiang
Chen, Ying-Pin
Bosch, Mathieu
Zou, Lanfang
Teat, Simon J.
Dalgarno, Scott J.
Zhou, Hong-Cai
A single crystalline porphyrinic titanium metal–organic framework
title A single crystalline porphyrinic titanium metal–organic framework
title_full A single crystalline porphyrinic titanium metal–organic framework
title_fullStr A single crystalline porphyrinic titanium metal–organic framework
title_full_unstemmed A single crystalline porphyrinic titanium metal–organic framework
title_short A single crystalline porphyrinic titanium metal–organic framework
title_sort single crystalline porphyrinic titanium metal–organic framework
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707486/
https://www.ncbi.nlm.nih.gov/pubmed/29218163
http://dx.doi.org/10.1039/c5sc00916b
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