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Revealing the thermodynamic driving force for ligand-based reductions in quinoids; conceptual rules for designing redox active and non-innocent ligands

Metal and ligand-based reductions have been modeled in octahedral ruthenium complexes revealing metal–ligand interactions as the profound driving force for the redox-active behaviour of orthoquinoid-type ligands. Through an extensive investigation of redox-active ligands we revealed the most critica...

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Detalles Bibliográficos
Autores principales:	Skara, G., Pinter, B., Geerlings, P., De Proft, F.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707504/ https://www.ncbi.nlm.nih.gov/pubmed/29218177 http://dx.doi.org/10.1039/c5sc01140j

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