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III-defined concepts in chemistry: rigid force constants vs. compliance constants as bond strength descriptors for the triple bond in diboryne
In a recent publication, the interpretation of Braunschweig's diboryne NHC–BB–NHC as a true triple bond is questioned. The analysis by Köppe and Schnöckel is based, inter alia, on the calculation of rigid coupling force constants. Nevertheless, since it is known for a long time that the use of...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Royal Society of Chemistry
2015
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707508/ https://www.ncbi.nlm.nih.gov/pubmed/29218174 http://dx.doi.org/10.1039/c5sc01322d |