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The boron–boron triple bond in NHC→B[triple bond, length as m-dash]B←NHC

Quantum chemical calculations of the compound B(2)(NHC(Me))(2) and a thorough examination of the electronic structure with an energy decomposition analysis provide strong evidence for the appearance of boron–boron triple bond character. This holds for the model compound and for the isolated diboryne...

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Detalles Bibliográficos
Autores principales:	Holzmann, Nicole, Hermann, Markus, Frenking, Gernot
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707517/ https://www.ncbi.nlm.nih.gov/pubmed/29218175 http://dx.doi.org/10.1039/c5sc01504a

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