Preorganized Ag(I) Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers

An Ag(I) dimer capped with labile organometallic diphosphorus ligands [Cp(2)Mo(2)(CO)(4)(η(2)‐P(2))] (Cp=C(5)H(5)) acts as a highly pre‐organized molecular precursor to direct the construction of 1D or 2D, and 3D organometallic–organic hybrid coordination polymers upon reaction with ditopic pyridine...

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Detalles Bibliográficos
Autores principales: Moussa, Mehdi Elsayed, Seidl, Michael, Balázs, Gábor, Zabel, Manfred, Virovets, Alexander V., Attenberger, Bianca, Schreiner, Andrea, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5708272/
https://www.ncbi.nlm.nih.gov/pubmed/28960509
http://dx.doi.org/10.1002/chem.201704582
Descripción
Sumario:An Ag(I) dimer capped with labile organometallic diphosphorus ligands [Cp(2)Mo(2)(CO)(4)(η(2)‐P(2))] (Cp=C(5)H(5)) acts as a highly pre‐organized molecular precursor to direct the construction of 1D or 2D, and 3D organometallic–organic hybrid coordination polymers upon reaction with ditopic pyridine‐based linkers. The formation of the supramolecular aggregates can be controlled by the stoichiometry of the organic molecules, and the mechanism is supported by DFT calculations.

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