Preorganized Ag(I) Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers

An Ag(I) dimer capped with labile organometallic diphosphorus ligands [Cp(2)Mo(2)(CO)(4)(η(2)‐P(2))] (Cp=C(5)H(5)) acts as a highly pre‐organized molecular precursor to direct the construction of 1D or 2D, and 3D organometallic–organic hybrid coordination polymers upon reaction with ditopic pyridine...

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Autores principales: Moussa, Mehdi Elsayed, Seidl, Michael, Balázs, Gábor, Zabel, Manfred, Virovets, Alexander V., Attenberger, Bianca, Schreiner, Andrea, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5708272/
https://www.ncbi.nlm.nih.gov/pubmed/28960509
http://dx.doi.org/10.1002/chem.201704582
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author Moussa, Mehdi Elsayed
Seidl, Michael
Balázs, Gábor
Zabel, Manfred
Virovets, Alexander V.
Attenberger, Bianca
Schreiner, Andrea
Scheer, Manfred
author_facet Moussa, Mehdi Elsayed
Seidl, Michael
Balázs, Gábor
Zabel, Manfred
Virovets, Alexander V.
Attenberger, Bianca
Schreiner, Andrea
Scheer, Manfred
author_sort Moussa, Mehdi Elsayed
collection PubMed
description An Ag(I) dimer capped with labile organometallic diphosphorus ligands [Cp(2)Mo(2)(CO)(4)(η(2)‐P(2))] (Cp=C(5)H(5)) acts as a highly pre‐organized molecular precursor to direct the construction of 1D or 2D, and 3D organometallic–organic hybrid coordination polymers upon reaction with ditopic pyridine‐based linkers. The formation of the supramolecular aggregates can be controlled by the stoichiometry of the organic molecules, and the mechanism is supported by DFT calculations.
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spelling pubmed-57082722017-12-04 Preorganized Ag(I) Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers Moussa, Mehdi Elsayed Seidl, Michael Balázs, Gábor Zabel, Manfred Virovets, Alexander V. Attenberger, Bianca Schreiner, Andrea Scheer, Manfred Chemistry Communications An Ag(I) dimer capped with labile organometallic diphosphorus ligands [Cp(2)Mo(2)(CO)(4)(η(2)‐P(2))] (Cp=C(5)H(5)) acts as a highly pre‐organized molecular precursor to direct the construction of 1D or 2D, and 3D organometallic–organic hybrid coordination polymers upon reaction with ditopic pyridine‐based linkers. The formation of the supramolecular aggregates can be controlled by the stoichiometry of the organic molecules, and the mechanism is supported by DFT calculations. John Wiley and Sons Inc. 2017-10-25 2017-11-16 /pmc/articles/PMC5708272/ /pubmed/28960509 http://dx.doi.org/10.1002/chem.201704582 Text en © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial‐NoDerivs (http://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Moussa, Mehdi Elsayed
Seidl, Michael
Balázs, Gábor
Zabel, Manfred
Virovets, Alexander V.
Attenberger, Bianca
Schreiner, Andrea
Scheer, Manfred
Preorganized Ag(I) Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers
title Preorganized Ag(I) Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers
title_full Preorganized Ag(I) Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers
title_fullStr Preorganized Ag(I) Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers
title_full_unstemmed Preorganized Ag(I) Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers
title_short Preorganized Ag(I) Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers
title_sort preorganized ag(i) bimetallic precursor with labile diphosphorus ligands for a programmed synthesis of organometallic–organic hybrid polymers
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5708272/
https://www.ncbi.nlm.nih.gov/pubmed/28960509
http://dx.doi.org/10.1002/chem.201704582
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