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A halogen-bonding-catalyzed Michael addition reaction
Only a few studies on the use of halogen bonding in catalysis have been published so far. Herein, (benz)imidazolium-based halogen bond donors are used as catalysts in a Michael addition reaction. The most potent catalyst, a rigid atropisomer featuring two iodobenzimidazolium moieties, provided a rat...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5708360/ https://www.ncbi.nlm.nih.gov/pubmed/29064505 http://dx.doi.org/10.1039/c7cc07175b |
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| author | Gliese, Jan-Philipp Jungbauer, Stefan H. Huber, Stefan M. |
| author_facet | Gliese, Jan-Philipp Jungbauer, Stefan H. Huber, Stefan M. |
| author_sort | Gliese, Jan-Philipp |
| collection | PubMed |
| description | Only a few studies on the use of halogen bonding in catalysis have been published so far. Herein, (benz)imidazolium-based halogen bond donors are used as catalysts in a Michael addition reaction. The most potent catalyst, a rigid atropisomer featuring two iodobenzimidazolium moieties, provided a rate acceleration versus a reference compound of ca. 50. |
| format | Online Article Text |
| id | pubmed-5708360 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2017 |
| publisher | Royal Society of Chemistry |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-57083602018-01-05 A halogen-bonding-catalyzed Michael addition reaction Gliese, Jan-Philipp Jungbauer, Stefan H. Huber, Stefan M. Chem Commun (Camb) Chemistry Only a few studies on the use of halogen bonding in catalysis have been published so far. Herein, (benz)imidazolium-based halogen bond donors are used as catalysts in a Michael addition reaction. The most potent catalyst, a rigid atropisomer featuring two iodobenzimidazolium moieties, provided a rate acceleration versus a reference compound of ca. 50. Royal Society of Chemistry 2017-11-14 2017-10-24 /pmc/articles/PMC5708360/ /pubmed/29064505 http://dx.doi.org/10.1039/c7cc07175b Text en This journal is © The Royal Society of Chemistry 2017 http://creativecommons.org/licenses/by-nc/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0) |
| spellingShingle | Chemistry Gliese, Jan-Philipp Jungbauer, Stefan H. Huber, Stefan M. A halogen-bonding-catalyzed Michael addition reaction |
| title | A halogen-bonding-catalyzed Michael addition reaction
|
| title_full | A halogen-bonding-catalyzed Michael addition reaction
|
| title_fullStr | A halogen-bonding-catalyzed Michael addition reaction
|
| title_full_unstemmed | A halogen-bonding-catalyzed Michael addition reaction
|
| title_short | A halogen-bonding-catalyzed Michael addition reaction
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| title_sort | halogen-bonding-catalyzed michael addition reaction |
| topic | Chemistry |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5708360/ https://www.ncbi.nlm.nih.gov/pubmed/29064505 http://dx.doi.org/10.1039/c7cc07175b |
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