Synthesis and applications of MANs/poly(MMA-co-BA) nanocomposite latex by miniemulsion polymerization

We have synthesized core-shell structured 3-methacryloxypropyltrimethoxysilane (MPS) functionalized antimony-doped tin oxide nanoparticles (MANs)–poly(methyl methacrylate-co-butyl acrylate) (PMMA-co-BA, PMB) nanocomposite latex particles via miniemulsion polymerization method. Polymerizable anionic...

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Detalles Bibliográficos
Autores principales: Gong, Sheng, Chen, Huayao, Zhou, Xinhua, Gunasekaran, Sundaram
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society Publishing 2017
Materias:
Engineering
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5717650/
https://www.ncbi.nlm.nih.gov/pubmed/29291076
http://dx.doi.org/10.1098/rsos.170844
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author Gong, Sheng
Chen, Huayao
Zhou, Xinhua
Gunasekaran, Sundaram
author_facet Gong, Sheng
Chen, Huayao
Zhou, Xinhua
Gunasekaran, Sundaram
author_sort Gong, Sheng
collection PubMed
description We have synthesized core-shell structured 3-methacryloxypropyltrimethoxysilane (MPS) functionalized antimony-doped tin oxide nanoparticles (MANs)–poly(methyl methacrylate-co-butyl acrylate) (PMMA-co-BA, PMB) nanocomposite latex particles via miniemulsion polymerization method. Polymerizable anionic surfactant DNS-86 (allyloxy polyoxyethylene(10) nonyl ammonium sulfate) was first introduced to synthesize core-shell nanocomposite. The morphologies of synthesized MANs and MANs/PMB latex nanocomposite particles were studied with transmission electron microscopy, which revealed particles, on average 70 nm in size, with a core-shell structure. Owing to the uniformity and hydrophobicity of MANs, the MANs-embedded PMB latex nanocomposite can be tailored more precisely than other nanoparticles-embedded nanocomposites. Films incorporating 10 wt% of MANs in the MAN/PMB latex nanocomposite exhibit good transmittance in the visible region, and excellent opacity in the near infrared region. The MANs/PMB nanocomposite film also appears suitable for heat insulation applications.
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spelling pubmed-57176502017-12-29 Synthesis and applications of MANs/poly(MMA-co-BA) nanocomposite latex by miniemulsion polymerization Gong, Sheng Chen, Huayao Zhou, Xinhua Gunasekaran, Sundaram R Soc Open Sci Engineering We have synthesized core-shell structured 3-methacryloxypropyltrimethoxysilane (MPS) functionalized antimony-doped tin oxide nanoparticles (MANs)–poly(methyl methacrylate-co-butyl acrylate) (PMMA-co-BA, PMB) nanocomposite latex particles via miniemulsion polymerization method. Polymerizable anionic surfactant DNS-86 (allyloxy polyoxyethylene(10) nonyl ammonium sulfate) was first introduced to synthesize core-shell nanocomposite. The morphologies of synthesized MANs and MANs/PMB latex nanocomposite particles were studied with transmission electron microscopy, which revealed particles, on average 70 nm in size, with a core-shell structure. Owing to the uniformity and hydrophobicity of MANs, the MANs-embedded PMB latex nanocomposite can be tailored more precisely than other nanoparticles-embedded nanocomposites. Films incorporating 10 wt% of MANs in the MAN/PMB latex nanocomposite exhibit good transmittance in the visible region, and excellent opacity in the near infrared region. The MANs/PMB nanocomposite film also appears suitable for heat insulation applications. The Royal Society Publishing 2017-11-01 /pmc/articles/PMC5717650/ /pubmed/29291076 http://dx.doi.org/10.1098/rsos.170844 Text en © 2017 The Authors. http://creativecommons.org/licenses/by/4.0/ Published by the Royal Society under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by/4.0/, which permits unrestricted use, provided the original author and source are credited.
spellingShingle Engineering
Gong, Sheng
Chen, Huayao
Zhou, Xinhua
Gunasekaran, Sundaram
Synthesis and applications of MANs/poly(MMA-co-BA) nanocomposite latex by miniemulsion polymerization
title Synthesis and applications of MANs/poly(MMA-co-BA) nanocomposite latex by miniemulsion polymerization
title_full Synthesis and applications of MANs/poly(MMA-co-BA) nanocomposite latex by miniemulsion polymerization
title_fullStr Synthesis and applications of MANs/poly(MMA-co-BA) nanocomposite latex by miniemulsion polymerization
title_full_unstemmed Synthesis and applications of MANs/poly(MMA-co-BA) nanocomposite latex by miniemulsion polymerization
title_short Synthesis and applications of MANs/poly(MMA-co-BA) nanocomposite latex by miniemulsion polymerization
title_sort synthesis and applications of mans/poly(mma-co-ba) nanocomposite latex by miniemulsion polymerization
topic Engineering
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5717650/
https://www.ncbi.nlm.nih.gov/pubmed/29291076
http://dx.doi.org/10.1098/rsos.170844
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