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Uncovering a reconstructive solid–solid phase transition in a metal–organic framework

A nanoporous three-dimensional metal–organic framework (MOF), ZnPurBr undergoes a transition to a previously unreported high-temperature phase, ZnPurBr-ht. The transition, which proceeds without mass loss, is uncovered through the use of differential scanning calorimetry (DSC). The new crystal struc...

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Detalles Bibliográficos
Autores principales: Longley, L., Li, N., Wei, F., Bennett, T. D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society Publishing 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5717694/
https://www.ncbi.nlm.nih.gov/pubmed/29291119
http://dx.doi.org/10.1098/rsos.171355