A crystalline anionic complex of scandium nitride endometallofullerene: experimental observation of single-bonded (Sc(3)N@I(h)-C(80)(–))(2) dimers

Reduction of scandium nitride clusterfullerene, Sc(3)N@I(h)-C(80), by sodium fluorenone ketyl in the presence of cryptand[2,2,2] allows the crystallization of the {cryptand[2,2,2](Na(+))}(2)(Sc(3)N@I(h)-C(80)(–))(2)·2.5C(6)H(4)Cl(2) (1) salt. The Sc(3)N@I(h)-C(80)˙(–) radical anions are dimerized to...

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Detalles Bibliográficos
Autores principales: Konarev, Dmitri V., Zorina, Leokadiya V., Khasanov, Salavat S., Popov, Alexey A., Otsuka, Akihiro, Yamochi, Hideki, Saito, Gunzi, Lyubovskaya, Rimma N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730043/
https://www.ncbi.nlm.nih.gov/pubmed/27511304
http://dx.doi.org/10.1039/c6cc05550h
Descripción
Sumario:Reduction of scandium nitride clusterfullerene, Sc(3)N@I(h)-C(80), by sodium fluorenone ketyl in the presence of cryptand[2,2,2] allows the crystallization of the {cryptand[2,2,2](Na(+))}(2)(Sc(3)N@I(h)-C(80)(–))(2)·2.5C(6)H(4)Cl(2) (1) salt. The Sc(3)N@I(h)-C(80)˙(–) radical anions are dimerized to form single-bonded (Sc(3)N@I(h)-C(80)(–))(2) dimers.

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