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A crystalline anionic complex of scandium nitride endometallofullerene: experimental observation of single-bonded (Sc(3)N@I(h)-C(80)(–))(2) dimers
Reduction of scandium nitride clusterfullerene, Sc(3)N@I(h)-C(80), by sodium fluorenone ketyl in the presence of cryptand[2,2,2] allows the crystallization of the {cryptand[2,2,2](Na(+))}(2)(Sc(3)N@I(h)-C(80)(–))(2)·2.5C(6)H(4)Cl(2) (1) salt. The Sc(3)N@I(h)-C(80)˙(–) radical anions are dimerized to...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730043/ https://www.ncbi.nlm.nih.gov/pubmed/27511304 http://dx.doi.org/10.1039/c6cc05550h |
| _version_ | 1783286290558484480 |
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| author | Konarev, Dmitri V. Zorina, Leokadiya V. Khasanov, Salavat S. Popov, Alexey A. Otsuka, Akihiro Yamochi, Hideki Saito, Gunzi Lyubovskaya, Rimma N. |
| author_facet | Konarev, Dmitri V. Zorina, Leokadiya V. Khasanov, Salavat S. Popov, Alexey A. Otsuka, Akihiro Yamochi, Hideki Saito, Gunzi Lyubovskaya, Rimma N. |
| author_sort | Konarev, Dmitri V. |
| collection | PubMed |
| description | Reduction of scandium nitride clusterfullerene, Sc(3)N@I(h)-C(80), by sodium fluorenone ketyl in the presence of cryptand[2,2,2] allows the crystallization of the {cryptand[2,2,2](Na(+))}(2)(Sc(3)N@I(h)-C(80)(–))(2)·2.5C(6)H(4)Cl(2) (1) salt. The Sc(3)N@I(h)-C(80)˙(–) radical anions are dimerized to form single-bonded (Sc(3)N@I(h)-C(80)(–))(2) dimers. |
| format | Online Article Text |
| id | pubmed-5730043 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2016 |
| publisher | Royal Society of Chemistry |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-57300432017-12-14 A crystalline anionic complex of scandium nitride endometallofullerene: experimental observation of single-bonded (Sc(3)N@I(h)-C(80)(–))(2) dimers Konarev, Dmitri V. Zorina, Leokadiya V. Khasanov, Salavat S. Popov, Alexey A. Otsuka, Akihiro Yamochi, Hideki Saito, Gunzi Lyubovskaya, Rimma N. Chem Commun (Camb) Chemistry Reduction of scandium nitride clusterfullerene, Sc(3)N@I(h)-C(80), by sodium fluorenone ketyl in the presence of cryptand[2,2,2] allows the crystallization of the {cryptand[2,2,2](Na(+))}(2)(Sc(3)N@I(h)-C(80)(–))(2)·2.5C(6)H(4)Cl(2) (1) salt. The Sc(3)N@I(h)-C(80)˙(–) radical anions are dimerized to form single-bonded (Sc(3)N@I(h)-C(80)(–))(2) dimers. Royal Society of Chemistry 2016-09-14 2016-08-04 /pmc/articles/PMC5730043/ /pubmed/27511304 http://dx.doi.org/10.1039/c6cc05550h Text en This journal is © The Royal Society of Chemistry 2016 http://creativecommons.org/licenses/by-nc/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0) |
| spellingShingle | Chemistry Konarev, Dmitri V. Zorina, Leokadiya V. Khasanov, Salavat S. Popov, Alexey A. Otsuka, Akihiro Yamochi, Hideki Saito, Gunzi Lyubovskaya, Rimma N. A crystalline anionic complex of scandium nitride endometallofullerene: experimental observation of single-bonded (Sc(3)N@I(h)-C(80)(–))(2) dimers |
| title | A crystalline anionic complex of scandium nitride endometallofullerene: experimental observation of single-bonded (Sc(3)N@I(h)-C(80)(–))(2) dimers
|
| title_full | A crystalline anionic complex of scandium nitride endometallofullerene: experimental observation of single-bonded (Sc(3)N@I(h)-C(80)(–))(2) dimers
|
| title_fullStr | A crystalline anionic complex of scandium nitride endometallofullerene: experimental observation of single-bonded (Sc(3)N@I(h)-C(80)(–))(2) dimers
|
| title_full_unstemmed | A crystalline anionic complex of scandium nitride endometallofullerene: experimental observation of single-bonded (Sc(3)N@I(h)-C(80)(–))(2) dimers
|
| title_short | A crystalline anionic complex of scandium nitride endometallofullerene: experimental observation of single-bonded (Sc(3)N@I(h)-C(80)(–))(2) dimers
|
| title_sort | crystalline anionic complex of scandium nitride endometallofullerene: experimental observation of single-bonded (sc(3)n@i(h)-c(80)(–))(2) dimers |
| topic | Chemistry |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730043/ https://www.ncbi.nlm.nih.gov/pubmed/27511304 http://dx.doi.org/10.1039/c6cc05550h |
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